Conductivities and crystal structures of BCEE-TTF salts

被引:1
作者
Tanaka, M [1 ]
Aya, T
Fukunaga, T
Kashino, S
机构
[1] Nagoya Univ, Sch Informat & Sci, Dept Nat Sci & Informat, Chikusa Ku, Nagoya, Aichi 4648601, Japan
[2] Okayama Univ, Fac Sci, Dept Chem, Okayama 7008530, Japan
关键词
conductivity; X-ray diffraction; organic conductors; electrochemical doping;
D O I
10.1016/S0379-6779(00)00706-2
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
2,3-B is(cyanoethylthio)6,7-(ethylenedithio)tetrathiafulvalene (BCEE-TTF) has the structure of the unsymmmetrical TTF derivative and the electrical properties of its radical-cation salts with AuBr2 and PF6 were studied. The PF6 salt show s the metallic behavior and has the high electrical conductivity at room temperature, although the PF6 salt becomes the insulator at low temperature. The crystal structure of the AuBr2 salt was also investigated.
引用
收藏
页码:745 / 746
页数:2
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