Solid phase synthesis of nitrogen and phosphor co-doped carbon quantum dots for sensing Fe3+ and the enhanced photocatalytic degradation of dyes

被引:106
作者
Guo, Yongming [1 ]
Cao, Fengpu [1 ]
Li, Yabo [1 ]
机构
[1] Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Peoples R China
基金
中国国家自然科学基金;
关键词
Solid phase synthesis; Carbon quantum dots; Fe3+; Photocatalytic degradation; Detection; HIGHLY SENSITIVE DETECTION; FLUORESCENT NANOMATERIALS; SELECTIVE DETECTION; OPTICAL-PROPERTIES; FACILE SYNTHESIS; METAL-IONS; ONE-POT; PROBE; NANOPARTICLES; GREEN;
D O I
10.1016/j.snb.2017.08.104
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A facile and one-step strategy has been developed for the preparation of highly fluorescent nitrogen and phosphor co-doped carbon quantum dots (NP-CQDs) through the thermal treatment of the mixture of citric acid and O-phosphorylethanolamine. The as-prepared NP-CQDs emit strong blue-green light under irradiation of 365 nm light and show emission maxima at 475 nm in aqueous solution. And these NP-CQDs exhibit great stability in high-salt conditions, excellent photostability and a high quantum yield of about 8.45%. Interestingly, the NP-CQDs have been successfully utilized for the sensitive and selective fluorometric detection of Fe3+ without interference from other ions in aqueous solution. Moreover, we have found that the NP-CQDs can enhance the photocatalytic activity of TiO2 for the degradation of dyes under simulated sunlight irradiation. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:1105 / 1111
页数:7
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