CdS nanocomposites assembled in porous phosphate heterostructures for fingerprint detection

被引:47
作者
Algarra, M. [2 ]
Jimenez-Jimenez, J. [3 ]
Moreno-Tost, R. [3 ]
Campos, B. B. [1 ]
Esteves da Silva, J. C. G. [1 ]
机构
[1] Univ Porto, Fac Ciencias, Ctr Invest Quim CIQ UP, P-4169007 Oporto, Portugal
[2] Univ Porto, Fac Ciencias, Ctr Geol, P-4169007 Oporto, Portugal
[3] Univ Malaga, Fac Ciencias, Dept Quim Inorgan, E-29071 Malaga, Spain
关键词
Nanocomposites; CdS quantum dots; Porous phosphate heterostructures; Fluorescence; Fingerprint analysis; QUANTUM DOTS; NANOCRYSTALS; NANOPARTICLE; FINGERMARKS; OXIDE;
D O I
10.1016/j.optmat.2011.01.017
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A fluorescent hybrid cadmium sulfide quantum dots (QDs) nanocomposites assembled in a porous phosphate heterostructures (PPH) functionalized with mercaptopropyl (PPH-SH) and propionitrile (PPH-CN) where synthesised in water and show high stability. Both materials, show fluorescence in the 450700 nm wavelength range but the PPH-SH-CdS is about five times more fluorescent than PPH-CN-CdS. The maximum emission wavelengths of the resulting materials are 576 nm (PPH-SH-CdS) and 616 nm (PPH-CN-CdS) and show Stokes shifts higher than 300 nm. The nanocomposites were characterized by TEM. EDS, FT-IR, XRD and fluorescence. These materials are suitable for fingerprint analysis. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:893 / 898
页数:6
相关论文
共 49 条
[1]   Semiconductor clusters, nanocrystals, and quantum dots [J].
Alivisatos, AP .
SCIENCE, 1996, 271 (5251) :933-937
[2]   The use of nanocrystals in biological detection [J].
Alivisatos, P .
NATURE BIOTECHNOLOGY, 2004, 22 (01) :47-52
[3]   Use of quantum dots in aqueous solution to detect blood fingermarks on non-porous surfaces [J].
Becue, Andy ;
Moret, Sebastien ;
Champod, Christophe ;
Margot, Pierre .
FORENSIC SCIENCE INTERNATIONAL, 2009, 191 (1-3) :36-41
[4]   Semiconducting superlattices templated by molecular assemblies [J].
Braun, PV ;
Osenar, P ;
Stupp, SI .
NATURE, 1996, 380 (6572) :325-328
[5]   Fluorescent Properties of a Hybrid Cadmium Sulfide-Dendrimer Nanocomposite and its Quenching with Nitromethane [J].
Campos, Bruno B. ;
Algarra, Manuel ;
Esteves da Silva, Joaquim C. G. .
JOURNAL OF FLUORESCENCE, 2010, 20 (01) :143-151
[6]   Mercury(II) sensing based on the quenching of fluorescence of CdS-dendrimer nanocomposites [J].
Campos, Bruno B. ;
Algarra, Manuel ;
Alonso, Beatriz ;
Casado, Carmen M. ;
Esteves da Silva, Joaquim C. G. .
ANALYST, 2009, 134 (12) :2447-2452
[7]  
Champod C., 2004, FINGERPRINTS OTHER R
[8]  
Cheeseman R., 1999, Journal of Forensic identification, V49, P261
[9]   Luminescent CdS quantum dots as selective ion probes [J].
Chen, YF ;
Rosenzweig, Z .
ANALYTICAL CHEMISTRY, 2002, 74 (19) :5132-5138
[10]  
Choi M.J., 2006, J FORENSIC IDENT, V56, P24