Graded PVD Mo-Si interlayer between Si coating and Mo-Si-B alloys: Investigation of oxidation behaviour

被引:9
作者
Anton, Ronja [1 ]
Huning, Steffen [2 ]
Laska, Nadine [1 ]
Weber, Matthias [3 ]
Schellert, Steven [3 ]
Gorr, Bronislava [4 ]
Christ, Hans-Jurgen [3 ]
Schulz, Uwe [1 ]
机构
[1] German Aerosp Ctr DLR, Inst Mat Res, D-51147 Cologne, Germany
[2] Tech Univ TU Dortmund, Now LIMO GmbH, D-44319 Dortmund, Germany
[3] Univ Siegen, Inst Mat Engn, D-57076 Siegen, Germany
[4] Karlsruhe Inst Technol KIT, Inst Appl Mat Appl Mat Phys, D-76334 Karlsruhe, Germany
关键词
Physical vapour deposition; Silicon dioxide; Oxidation protection; Silicon; Mo-silicide; MOLYBDENUM SILICIDES; BARRIER COATINGS; TEMPERATURE; RESISTANCE; FRACTURE; SILICON; GROWTH; MICROSTRUCTURE; CHEMISTRY; DIFFUSION;
D O I
10.1016/j.corsci.2021.109843
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The insufficient oxidation resistance of Mo-Si-B alloys at high temperatures inevitably requires a protective coating. A dual layer system combining a graded Mo-Si interlayer with a Si oxidation protective top layer has been applied by magnetron sputtering on a Mo-9Si-8B alloy. The interlayer architecture was designed to maximize the adhesion between top layer and substrate by creating thermodynamic compatibility between alloy and Si. Isothermal oxidation tests at 800 and 1200 degrees C in air up to 300 h were performed focusing on chemical reactions between top layer, interlayer and substrate as well as the evolution of the thermally grown SiO2.
引用
收藏
页数:12
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