Kinetic and Mechanistic Similarities between Reversible Addition Fragmentation Chain Transfer Intermediate and Acrylate Midchain Radicals

被引：21

作者：

Barner-Kowollik, Christopher ^{[1
]}

Junkers, Tanja ^{[2
]}

机构：

[1] KIT, Inst Tech Chem & Polymerchem, Engesserstr 18, D-76128 Karlsruhe, Germany

[2] Univ Hasselt, Inst Mat Res, B-3590 Diepenbeek, Belgium

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2011年 / 49卷 / 05期

关键词：

acrylate free radical polymerization; kinetics (polym.); macromonomers; midchain radicals (MCRs); reversible addition fragmentation chain transfer (RAFT); PULSED-LASER; POLY(BUTYL ACRYLATE); RATE COEFFICIENTS; MASS-SPECTROMETRY; BUTYL ACRYLATE; POLYMERIZATION; PROPAGATION; SECONDARY;

D O I：

10.1002/pola.24546

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This contribution highlights the mechanistic and kinetic similarities as well as differences between midchain radicals occurring in both acrylate free radical polymerization as well as reversible addition fragmentation chain transfer mediated processes. © 2011 Wiley Periodicals, Inc.

引用

页码：1293 / 1297

页数：5

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