A simple fluorescent-colorimetric probe for selective switch-on detection of Al3+ in ethanol

被引:16
作者
Liu, Cong [1 ]
Liu, Li-mei [1 ]
Li, Tian-rong [1 ]
Liu, Kui [1 ,2 ]
Yang, Zheng-yin [1 ]
机构
[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China
[2] Tianshui Normal Univ, Coll Chem Engn & Technol, Tianshui 741001, Gansu, Peoples R China
基金
中国国家自然科学基金;
关键词
Fluorescent probe; Aluminum ion; Colorimetric; Test kits; TURN-ON; SCHIFF-BASE; ALUMINUM ACCUMULATION; CHEMOSENSOR; SENSOR; IONS; ZN2+; SENSITIVITY; DIARYLETHENE;
D O I
10.1016/j.ica.2019.119327
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel and simple fluorescent probe, 7-methoxychromone-3-carbaldehyde-(3'4'5'-trimethoxybenzoyl) hydrazone (L), was designed and synthesized. The probe L presented outstanding "turn-on" fluorescence response towards Al3+ over most other competitive ions in ethanol. The detection limit of L for recognizing Al3+ was measured to be 2.14 x 10(-7) M. According to these excellent properties, the detecting of Al3+ on filter papers was studied successfully. Photoinduced electron transfer (PET) process, coupled with the C=N isomerisation process, is put forward to interpret the obvious fluorescence response.
引用
收藏
页数:6
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