Development of chiral N,N-ditopic metalloligands based on a Cinchona alkaloids' backbone for constructing homochiral coordination polymers

被引:17
|
作者
Lewinski, Janusz [1 ,2 ]
Kaczorowski, Tomasz [1 ,2 ]
Justyniak, Iwona [2 ]
Prochowicz, Daniel [1 ]
机构
[1] Warsaw Univ Technol, Dept Chem, PL-00664 Warsaw, Poland
[2] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland
关键词
METAL-ORGANIC FRAMEWORKS; BUILDING-BLOCKS; LIGANDS; COMPLEXES; CATALYSIS; ORGANOALUMINUM; BIPYRIDINE; SEPARATION; MOLECULES;
D O I
10.1039/c0cc03586f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The bimetallic chiral bipyridyl-type metalloligands based on aluminium derivatives of cinchonine, [R2Al(mu-CN)](2) (R = Me or Et), in combination with the corresponding ZnR2 compound as nodes were used for the generation of novel homochiral heterometallic coordination polymers of either zig-zag or helical topology, depending on the character of the R substituent.
引用
收藏
页码:950 / 952
页数:3
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