The rhodium-catalyzed Pauson-Khand reaction

被引：141

作者：

Kobayashi, T ^{[1
]}

Koga, Y ^{[1
]}

Narasaka, K ^{[1
]}

机构：

[1] Univ Tokyo, Dept Chem, Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 624卷 / 1-2期

关键词：

Pauson-Khand reaction; rhodium; catalytic reaction; cyclopentenone;

D O I：

10.1016/S0022-328X(00)00835-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A rhodium carbonyl complex, [RhCl(CO)(2)](2), serves as a catalyst of the intra- and inter-molecular Pauson-Khand reaction. By the use of the rhodium catalyst, cyclopentenone derivatives are prepared from various 1,6- and 1,7-enynes under 1 arm of CO. Furthermore, this rhodium-catalyzed reaction is accelerated by reducing partial pressure of CO to less than 1 atm. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：73 / 87

页数：15

共 59 条

[1]

ADNO J, 1999, J AM CHEM SOC, V121, P7411

[2] Pauson-Khand reaction of activated olefins. [J].

Ahmar, M ;

Antras, F ;

Cazes, B .

TETRAHEDRON LETTERS, 1999, 40 (30) :5503-5506

[3] Cyclopropylmethyl alkyl acetic acids and their bactericidal action toward B. Leprae. XIII [J].

Arvin, JA ;

Adams, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1928, 50 :1983-1985

[4] Thermal promotion of the cobalt catalyzed intramolecular Pauson-Khand reaction - An alternative experimental protocol for cyclopentenone synthesis [J].

Belanger, DB ;

O'Mahony, DJR ;

Livinghouse, T .

TETRAHEDRON LETTERS, 1998, 39 (42) :7637-7640

[5] Hexacarbonyldicobalt-alkyne complexes as convenient Co2(CO)8 surrogates in the catalytic Pauson-Khand reaction [J].

Belanger, DB ;

Livinghouse, T .

TETRAHEDRON LETTERS, 1998, 39 (42) :7641-7644

[6] An intramolecular allenic [2+2+1]cycloaddition [J].

Brummond, KM ;

Wan, HH ;

Kent, JL .

JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (19) :6535-6545

[7] FISCHER CARBENE COMPLEXES FACILITATE THE INTRAMOLECULAR PAUSON-KHAND REACTION [J].

CAMPS, F ;

MORETO, JM ;

RICART, S ;

VINAS, JM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (11) :1470-1472

[8] PtCl2-catalyzed conversion of 1,6- and 1,7-enynes to 1-vinylcycloalkenes. Anomalous bond connection in skeletal reorganization of enynes [J].

Chatani, N ;

Furukawa, N ;

Sakurai, H ;

Murai, S .

ORGANOMETALLICS, 1996, 15 (03) :901-903

[9] HIGHLY SELECTIVE SKELETAL REORGANIZATION OF 1,6-ENYNE AND 1,7-ENYNE TO 1-VINYLCYCLOALKENES CATALYZED BY [RUCL2(CO)(3)](2) [J].

CHATANI, N ;

MORIMOTO, T ;

MUTO, T ;

MURAI, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (13) :6049-6050

[10]

Chung YK, 1999, COORDIN CHEM REV, V188, P297

← 1 2 3 4 5 6 →