Enantiocontrolled construction of tricyclic furan derivatives via an asymmetric Diels-Alder reaction

被引：9
|
作者：
Pai, CC [1 ]
Liu, RS [1 ]
机构：
[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30043, Taiwan
来源：
ORGANIC LETTERS | 2001年 / 3卷 / 09期
关键词：
D O I：
10.1021/ol015622j
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] The two enantiomers of trycyclic furan derivatives were prepared respectively from Diels-Alder reactions of oxycyclic dienes 3a and 3b, followed by degradation of the 2-(benzyloxy)ethyl group. Compounds 3a and 3b can be selectively synthesized by [3+2]-cycloaddition of vinylpropargyltungsten complex with (2S)-(benzyloxy)-propanal.
引用
收藏
页码：1295 / 1298
页数：4
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