Formation of Homo- and Heteronuclear Platinum(II) and Palladium(II) Carbene Complexes in the Reactions of Coordinated Isocyanides with Aminothiazaheterocycles

被引：12
|
作者：
Mikherdov, A. S. [1 ]
Orekhova, Yu. A. [1 ]
Boyarskii, V. P. [1 ]
机构：
[1] St Petersburg State Univ, Univ Skaya Nab 7-9, St Petersburg 199034, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2018年 / 88卷 / 10期
基金：
俄罗斯基础研究基金会;
关键词：
platinum(II) diaminocarbene complexes; palladium(II) diaminocarbene complexes; heteronuclear carbene complexes; isocyanide ligands; aminothiazaheterocycles; ACYCLIC DIAMINOCARBENE COMPLEXES; COPPER-FREE; EFFICIENT CATALYSTS; SONOGASHIRA; ISONITRILES; LIGANDS; GOLD(I);
D O I：
10.1134/S1070363218100158
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of 5-(trifluoromethyl)-1,3,4-thiadiazol-2-amine with cis-dichlorobis(2,6-dimethylphenyl isocyanide)platinum(II) (cis-[PtCl2(CNXyl)(2)], Xyl = 2,6-Me2C6H3) gave platinum(II) monocarbene complex whose deprotonation with an organic base generated a nucleophilic species capable of reacting with palladium(II) and platinum(II) bis(isocyanide) complexes to afford homo- and heteronuclear isocyanide/carbene structures.
引用
收藏
页码：2119 / 2124
页数：6
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