Bright blue organic light-emitting diode with improved color purity using a LiF/Al cathode

被引:279
作者
Shaheen, SE [1 ]
Jabbour, GE
Morrell, MM
Kawabe, Y
Kippelen, B
Peyghambarian, N
Nabor, MF
Schlaf, R
Mash, EA
Armstrong, NR
机构
[1] Univ Arizona, Ctr Opt Sci, Tucson, AZ 85721 USA
[2] Univ Arizona, Dept Chem, Tucson, AZ 85721 USA
关键词
D O I
10.1063/1.368299
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report a two-layer, blue organic light-emitting diode with a 4,4'-bis(2,2-diphenylvinyl)-1,1'-biphenyl emission layer and a LiF/Al cathode which has an external quantum efficiency of 1.4% and a maximum luminance of 3000 cd/m(2). Insertion of the thin LiF layer results in a 50-fold increase in the device efficiency compared to a device with an aluminum only cathode, and eliminates the need for an electron-transporting layer, such as tris(8-hydroxyquinoline)aluminum. This results in a device with excellent color purity with an emission peak at 476 nm and a full width at half maximum of 78 nm. Using ultraviolet photoelectron spectroscopy, we find that the effective work-function of aluminum decreases dramatically with sub-monolayer amounts of LiF deposited on the surface. (C) 1998 American Institute of Physics. [S0021-8979(98)05816-2].
引用
收藏
页码:2324 / 2327
页数:4
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