Liquid-liquid interface in a binary mixture of associating fluids exhibiting a closed-loop immiscibility

被引:8
作者
Bucior, K [1 ]
Patrykiejew, A
Sokolowski, S
Pizio, O
机构
[1] Marie Curie Sklodowska Univ, Dept Modelling Physicochem Proc, PL-20031 Lublin, Poland
[2] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City, DF, Mexico
关键词
D O I
10.1080/0026897031000112505
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We investigate the structure and thermodynamic properties of the liquid-liquid interface for a two-component mixture of associating fluids, exhibiting the closed-loop liquid-liquid immiscibility. In the study we apply the density functional approach and evaluate the density profiles, the ratio of unbound particles and the surface tension in order to investigate how those properties depend on the association energy.
引用
收藏
页码:2233 / 2240
页数:8
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