Novel biodegradable polymeric flocculant based on polyacrylamide-grafted tamarind kernel polysaccharide

被引:96
作者
Ghosh, Sandipta [2 ]
Sen, Gautam [2 ]
Jha, U. [2 ]
Pal, Sagar [1 ]
机构
[1] Indian Sch Mines, Dept Appl Chem, Dhanbad 826004, Jharkhand, India
[2] Birla Inst Technol, Dept Appl Chem, Ranchi 835215, Jharkhand, India
关键词
Flocculation; Graft copolymer; Tamarind kernel polysaccharide; Turbidity; Wastewater; INITIATED SYNTHESIS; DRUG-DELIVERY; STARCH; CARBOXYMETHYLSTARCH; IRRADIATION; COPOLYMERS; EFFLUENT; RELEASE; GUM;
D O I
10.1016/j.biortech.2010.07.058
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Novel biodegradable polymeric flocculants were produced by conventional redox grafting, microwave-initiated and microwave-assisted grafting of acrylamide to tamarind kernel polysaccharide (TKP). The graft copolymers were characterized by viscometry, elemental analysis, molecular weight determination using SLS analysis, and NMR spectroscopy. The flocculation efficiency of the grafting products in kaolin suspension, municipal sewage wastewater and textile industry wastewater was primarily dependent on the length of the grafted polyacrylamide chain. The flocculant obtained by microwave-assisted grafting method was superior to TKP and polyacrylamide-based commercial flocculant (Rishfloc 226 LV) in flocculation tests. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:9638 / 9644
页数:7
相关论文
共 30 条
  • [1] A model of flocculation
    Brostow, Witold
    Pal, Sagar
    Singh, Ram P.
    [J]. MATERIALS LETTERS, 2007, 61 (22) : 4381 - 4384
  • [2] Bioremediation of polycyclic aromatic hydrocarbon (PAH)-contaminated waste using composting approaches
    Antizar-Ladislao, B
    Lopez-Real, JM
    Beck, AJ
    [J]. CRITICAL REVIEWS IN ENVIRONMENTAL SCIENCE AND TECHNOLOGY, 2004, 34 (03) : 249 - 289
  • [3] Starch granules: structure and biosynthesis
    Buleon, A
    Colonna, P
    Planchot, V
    Ball, S
    [J]. INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 1998, 23 (02) : 85 - 112
  • [4] Synthesis of crosslinked starch-graft-polyacrylamide-co-sodium xanthate and its performances in wastewater treatment
    Chang, Qing
    Hao, Xuekui
    Duan, Lili
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2008, 159 (2-3) : 548 - 553
  • [5] Graft copolymerisation of acrylamide onto cashew gum
    da Silva, Durcilene A.
    de Paula, Regina C. M.
    Feitosa, Judith P. A.
    [J]. EUROPEAN POLYMER JOURNAL, 2007, 43 (06) : 2620 - 2629
  • [6] Microwave chemistry
    Galema, SA
    [J]. CHEMICAL SOCIETY REVIEWS, 1997, 26 (03) : 233 - 238
  • [7] Bioadhesive grafted starch copolymers as platforms for peroral drug delivery: a study of theophylline release
    Geresh, S
    Gdalevsky, GY
    Gilboa, L
    Voorspoels, J
    Remon, JP
    Kost, J
    [J]. JOURNAL OF CONTROLLED RELEASE, 2004, 94 (2-3) : 391 - 399
  • [8] Greene DL, 1999, ENERGY J, V20, P1
  • [9] ENERGETICS OF FLOCCULATION + REDISPERSION BY POLYMERS
    HEALY, TW
    LAMER, VK
    [J]. JOURNAL OF COLLOID SCIENCE, 1964, 19 (04): : 323 - &
  • [10] MECHANISM OF OXIDATION OF CYCLIC ALCOHOLS BY CERIUM(4)
    HINTZ, HL
    JOHNSON, DC
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (03) : 556 - &