PEG-6000 Assisted Growth of Copper Dendrites

被引:2
作者
Li, Zhongchun [1 ,2 ]
Zhou, Quanfa [1 ,2 ]
机构
[1] Jiangsu Key Lab Precious Met Chem, Changzhou 213001, Peoples R China
[2] Jiangsu Teachers Univ Technol, Sch Chem & Chem Engn, Changzhou, Peoples R China
关键词
Copper; dendrite; PEG-6000; synthesis; ORIENTED ATTACHMENT; SHAPE CONTROL; NANOPARTICLES; NANOWIRES; MECHANISM; NANOCRYSTALS; NANORODS; SURFACE; FUTURE;
D O I
10.1080/01932690903269545
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Highly uniform copper dendrites were successfully prepared in large quantities by a simple wet chemical approach using hydrazine hydrate as reducant in the presence of polyethylene glycol 6000 (PEG-6000) at room temperature. Scanning electron microscopy (SEM), ultraviolet (UV)-vis absorption spectroscopy, and x-ray diffraction (XRD) have been used to characterize the obtained products. It is found that the architecture of copper particles is drastically influenced by the mass ratio of PEG-6000/CuSO4(aq), PEG-6000/N2H4 center dot H2O, CuSO4(aq)/N2H4 center dot H2O and the concentration of precursors. It is revealed that PEG-6000 might play both capping reagent and dispersion reagent roles.
引用
收藏
页码:1401 / 1404
页数:4
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