A novel microwave-assisted synthesis of RuO2-TiO2 electrodes with improved chlorine and oxygen evolutions

被引:6
作者
Tran Le Luu [1 ]
Kim, Jiye [2 ]
Yoon, Jeyong [2 ]
机构
[1] Vietnamese German Univ, Dept Mechatron & Sensor Syst Technol, Hoa Phu Ward, Le Lai St, Thu Dau Mot City, Binh Duong Prov, Vietnam
[2] Seoul Natl Univ, Sch Chem & Biol Engn, Seoul 151742, South Korea
关键词
RuO2; Electrocatalyst; Sol-gel; Microwave; Chlorine; Oxygen evolution; SOL-GEL; ACTIVE SURFACE; RUO2; MORPHOLOGY; NANOTUBES; MECHANISM; COATINGS;
D O I
10.5004/dwt.2017.20671
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
RuO2-TiO2 electrode now becomes popular in the chlor-alkali industry because of high electrocatalytic and stability with chlorine and oxygen evolutions. Using alternative green method for preparation of RuO2-TiO2 electrode is necessary to reduce the cost, time, increase the electrocatalyst performance, stability, and environmental compatibility. In this study, the Ti/RuO2-TiO2 electrodes were synthesized using sol-gel method under microwave irradiation and investigated for the anodic chlorine and oxygen evolutions. This method can produce small size and uniform distribution of RuO2-TiO2 nanoparticles with mean diameter of 8-10 nm on the big crack size surface, which contributes for the increasing of outer active surface area. The chlorine, oxygen evolution efficiency, and stability comparisons show considerably higher for microwave-assisted electrodes than for those obtained by the conventional heating method. Microwave-assisted sol-gel route has been identified as a novel and powerful method for quick synthesis of RuO2-TiO2 electrodes with excellent chlorine and oxygen evolution performances.
引用
收藏
页码:105 / 111
页数:7
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