N-heterocyclic carbene-palladium complexes as efficient catalysts for the oxidative carbonylation of Amines to ureas

被引:25
作者
Zheng, Shuzhan
Peng, Xingao
Liu, Jianming
Sun, Wei
Xia, Chungu [1 ]
机构
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synthet & Select Oxidat, Lanzhou 730000, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
关键词
D O I
10.1002/hlca.200790152
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A highly efficient oxidative carbonylation reaction of amines to ureas was developed making use of carbene -palladium complexes in the absence of any promoter. Both aliphatic amines and aromatic amines were transformed in good to excellent yields to the expected ureas.
引用
收藏
页码:1471 / 1476
页数:6
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