A simple nitration of electrophilic alkenes with tetranitromethane in the presence of triethylamine. Synthesis of functionalized β-nitroalkenes

被引：6
作者：
Volkova, Yulia A. [1 ]
Averina, Elena B. [1 ,2 ]
Grishin, Yuri K. [1 ]
Rybakov, Victor B. [1 ]
Kuznetsova, Tamara S. [1 ,2 ]
Zefirov, Nikolai S. [1 ,2 ]
机构：
[1] Lomonosov Moscow State Univ, Dept Chem, Moscow 119992, Russia
[2] IPhaC RAS, Chernogolovka 142432, Moscow Region, Russia
来源：
TETRAHEDRON LETTERS | 2011年 / 52卷 / 22期
基金：
俄罗斯基础研究基金会;
关键词：
Tetranitromethane; Electrophilic alkenes; beta-Nitroalcohols; beta-Nitroalkenes; DIELS-ALDER; CONJUGATED NITROALKENES; BETA(2)-AMINO ACIDS; NITRO ACRYLATES; NITROACRYLATES; CONVERSION; CYCLOADDITIONS; CHEMISTRY; REAGENT; OLEFINS;
D O I：
10.1016/j.tetlet.2011.04.012
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A convenient method for the preparation of functionalized beta-nitroalkenes based on the nitration of alpha,alpha-di- and alpha,alpha,beta-trisubstituted unsaturated aldehydes, ketones and esters with tetranitromethane in the presence of triethylamine is described. Series of substituted beta-nitroalcohols and beta-nitroalkenes are obtained in good yields under mild conditions. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2910 / 2913
页数：4
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