Bimetallic Pt-Cu catalysts for glycerol oxidation with oxygen in a base-free aqueous solution

被引：96
作者：
Liang, Dan [1 ]
Gao, Jing [1 ]
Wang, Junhua [1 ]
Chen, Ping [1 ]
Wei, Yanfei [2 ]
Hou, Zhaoyin [1 ]
机构：
[1] Zhejiang Univ, Inst Catalysis, Dept Chem, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310028, Zhejiang, Peoples R China
[2] Environm Sci Res & Design Inst Zhejiang Prov, Hangzhou 310020, Zhejiang, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2011年 / 12卷 / 12期
关键词：
Glycerol oxidation; Pt-Cu catalysts; Base-free; Carbon supports; SELECTIVE OXIDATION; PHASE OXIDATION; CARBON-MONOXIDE; AU CATALYSTS; PD; BEHAVIOR; BIODIESEL; ALCOHOLS; METALS;
D O I：
10.1016/j.catcom.2011.03.019
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A series of carbon supported bimetallic Pt-Cu catalysts were prepared and used for glycerol oxidation with oxygen in a base-free aqueous solution. It was found that bimetallic PtCu/C was more active than monometallic Pt/C towards selective oxidation of glycerol to glyceric acid. The selectivity of free glyceric acid reached 70.8% at an 86.2% conversion of glycerol over 5Pt-Cu/C. Highly dispersed bimetallic Pt-Cu nanoparticles with small particle size in dominant alloyed phase of PtCu(3) were confirmed by XRD and TEM in the bimetallic Pt-Cu/C catalyst, which is proposed to contribute to the improved performance. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：1059 / 1062
页数：4
相关论文
共 31 条
  • [1] Improved utilisation of renewable resources: New important derivatives of glycerol
    Behr, Arno
    Eilting, Jens
    Irawadi, Ken
    Leschinski, Julia
    Lindner, Falk
    [J]. GREEN CHEMISTRY, 2008, 10 (01) : 13 - 30
  • [2] Biodiesel production from crude Jatropha curcas L. seed oil with a high content of free fatty acids
    Berchmans, Hanny Johanes
    Hirata, Shizuko
    [J]. BIORESOURCE TECHNOLOGY, 2008, 99 (06) : 1716 - 1721
  • [3] Selective oxidation of alcohols and aldehydes on metal catalysts
    Besson, M
    Gallezot, P
    [J]. CATALYSIS TODAY, 2000, 57 (1-2) : 127 - 141
  • [4] Selective oxidation of glycerol with oxygen using mono and bimetallic catalysts based on Au, Pd and Pt metals
    Bianchi, CL
    Canton, P
    Dimitratos, N
    Porta, F
    Prati, L
    [J]. CATALYSIS TODAY, 2005, 102 : 203 - 212
  • [5] Application of copper-gold alloys in catalysis: current status and future perspectives
    Bracey, Charlotte L.
    Ellis, Peter R.
    Hutchings, Graham J.
    [J]. CHEMICAL SOCIETY REVIEWS, 2009, 38 (08) : 2231 - 2243
  • [6] Oxidation of glycerol using supported Pt, Pd and Au catalysts
    Carrettin, S
    McMorn, P
    Johnston, P
    Griffin, K
    Kiely, CJ
    Hutchings, GJ
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (06) : 1329 - 1336
  • [7] Selective oxidation of glycerol to glyceric acid using a gold catalyst in aqueous sodium hydroxide
    Carrettin, S
    McMorn, P
    Johnston, P
    Griffin, K
    Hutchings, GJ
    [J]. CHEMICAL COMMUNICATIONS, 2002, (07) : 696 - 697
  • [8] Investigation on the behaviour of Pt(0)/carbon and Pt(0),Au(0)/carbon catalysts employed in the oxidation of glycerol with molecular oxygen in water
    Dimitratos, N.
    Messi, C.
    Porta, F.
    Prati, L.
    Villa, A.
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 256 (1-2) : 21 - 28
  • [9] Pd and Pt catalysts modified by alloying with Au in the selective oxidation of alcohols
    Dimitratos, Nikolaos
    Villa, Alberto
    Wang, Di
    Porta, Francesca
    Su, Dangsheng
    Prati, Laura
    [J]. JOURNAL OF CATALYSIS, 2006, 244 (01) : 113 - 121
  • [10] Liquid Phase Oxidation of Glycerol Using a Single Phase (Au-Pd) Alloy Supported on Activated Carbon: Effect of Reaction Conditions
    Dimitratos, Nikolaos
    Villa, Alberto
    Prati, Laura
    [J]. CATALYSIS LETTERS, 2009, 133 (3-4) : 334 - 340
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