Self-organization of stack-up block copolymers into polymeric supramolecules

被引：1
|
作者：
Yuan, Yong J. [1 ]
Choi, Ka-Wai [1 ]
Wong, Herbert [1 ]
机构：
[1] Ind Res Ltd, Crown Res Inst, Lower Hutt 31310, New Zealand
来源：
NANOSCALE RESEARCH LETTERS | 2007年 / 2卷 / 02期
关键词：
self-assembly; block co-polymer; NMR;
D O I：
10.1007/s11671-007-9038-8
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Polyethylene oxide -b- polypropylene oxide -b- polyethylene oxide (EO106PO70EO106) block copolymer self-organizes into polymeric supramolecules, characterized by NMR as phase transition from the isotropic stack-up block structure to the ordered cubic polymeric supramolecular structure. Its dependence on both temperature and copolymer concentration is clearly shown by the changes in line shape and chemical shift of the PO70 block beta, gamma resonances.
引用
收藏
页码：104 / 106
页数：3
相关论文
共 50 条
  • [21] Effect of chain topology on the self-organization and dynamics of block copolypeptides: From diblock copolymers to stars
    Gitsas, A.
    Floudas, G.
    Mondeshki, M.
    Butt, H-J.
    Spiess, H. W.
    Iatrou, H.
    Hadjichristidis, N.
    BIOMACROMOLECULES, 2008, 9 (07) : 1959 - 1966
  • [22] BLOCK-COPOLYMERS WITH BIPYRIDINE CONTAINING SEGMENTS - SYNTHESIS AND SELF-ORGANIZATION BY CU(I) COMPLEXATION
    EISENBACH, CD
    GOLDEL, A
    TERSKANREINOLD, M
    SCHUBERT, US
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 1995, 196 (04) : 1077 - 1091
  • [23] Synthesis and self-organization of resorcinarene-core polylactide/polyethylene glycol star block copolymers
    Il'Giovine, Zachary J.
    Weaver, Tiffany L.
    Goudy, Victoria A.
    Corbin, Perry S.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 241
  • [24] The self-organization of diblock copolymers at polymer blend interfaces
    Schnell, R
    Stamm, M
    PHYSICA B, 1997, 234 : 247 - 249
  • [25] Self-organization of diblock copolymers at polymer blend interfaces
    Schnell, R.
    Stamm, M.
    Physica B: Condensed Matter, 1997, 234-236 : 247 - 249
  • [26] Self-organization of reconfigurable protocol stack for networked control systems
    Zhou C.-J.
    Chen H.
    Qin Y.-Q.
    Shi Y.-F.
    Yu G.-C.
    International Journal of Automation and Computing, 2011, 8 (02) : 221 - 235
  • [27] Self-organization of Reconfigurable Protocol Stack for Networked Control Systems
    Chun-Jie Zhou Hui Chen Yuan-Qing Qin Yu-Feng Shi Guang-Can Yu Key Laboratory of Ministry of Education for Image Processing and Intelligent Control
    International Journal of Automation & Computing, 2011, (02) : 221 - 235
  • [28] Self-organization of fullerene molecules in thin polymeric films
    Voznyakovskii, A. P.
    Kudoyarov, M. F.
    Piotrovskii, L. B.
    FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES, 2008, 16 (5-6) : 654 - 658
  • [29] Self-Organization of Polymeric Fluids in Strong Stress Fields
    Semakov, A. V.
    Kulichikhin, V. G.
    Malkin, A. Y.
    ADVANCES IN CONDENSED MATTER PHYSICS, 2015, 2015
  • [30] Self-organization process of ordered structures in linear and star poly(styrene)-poly(isoprene) block copolymers:: Gaussian models and mesoscopic parameters of polymeric systems
    Soto-Figueroa, Cesar
    Vicente, Luis
    Martinez-Magadan, Jose-Manuel
    Rodriguez-Hidalgo, Maria-del-Rosario
    JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (40): : 11756 - 11764
12345