Electrogenerated base-promoted synthesis and antimicrobial activity of 2-(1,3-dithian-2-ylidene)-2-arylacetonitrile and 2-(1,3-dithiolan-2-ylidene)-2-arylacetonitrile

被引：7

作者：

Hamrouni, Kaouthar ^{[1
]}

Saied, Taieb ^{[1
,2
]}

El Abed, Nariman ^{[3
]}

Ahmed, Sami Ben Hadj ^{[3
]}

Boujlel, Khaled ^{[1
]}

Ben Khoud, Mohamed Lamine ^{[1
]}

机构：

[1] Univ Tunis El Manar, Fac Sci Tunis, Lab Chim Analyt & Electrochim, Tunis, Tunisia

[2] Inst Natl Sci Appl & Technol, Dept Chim & Biol Appl, Tunis, Tunisia

[3] Univ Carthage, Inst Natl Sci Appl & Technol, Lab Prot & Mol Bioact Ingn, Ctr Urbain Nord, Tunis, Tunisia

来源：

JOURNAL OF SULFUR CHEMISTRY | 2015年 / 36卷 / 02期

关键词：

antimicrobial activity; carbone disulfur; 2-(1,3-dithian-2-ylidene)-2-arylacetonitrile; 2-(1,3-dithiol-2-ylidene)-2-arylacetonitrile; anion EGBs; CYANOMETHYL ANION; DERIVATIVES; OXAZOLIDIN-2-ONES; ESTERS; AMINES;

D O I：

10.1080/17415993.2015.1005620

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new preparation of 2-(1,3-dithian-2-ylidene)-2-arylacetonitrile and 2-(1,3-dithiol-2-ylidene)-2-arylacetonitrile is described. The electrogenerated cyanomethyl base/anion obtained from the electroreduction of acetonitrile promotes reactions between arylacetonitrile, carbon disulfide and 1-bromo-3-chloropropane or 1,2-dibromoethane. Obtained products have been identified according to their spectroscopic data (IR and H-1 NMR and C-13 NMR) and elemental analysis. The possible antibacterial activities of some of these compounds were investigated. Promising results were found against few types of bacteria.

引用

页码：196 / 206

页数：11

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