Tuning the bridging modes of Cu-azido complexes with Schiff bases by varying the terminal groups

被引：21

作者：

Zhang, Ji-Cai ^{[1
]}

Zhou, Xiao-Shuang ^{[1
]}

Wang, Xiao-Ling ^{[1
]}

Li, Xiao-Fang ^{[1
]}

You, Zhong-Lu ^{[1
]}

机构：

[1] Liaoning Normal Univ, Dept Chem & Chem Engn, Dalian 116029, Peoples R China

来源：

TRANSITION METAL CHEMISTRY | 2011年 / 36卷 / 01期

关键词：

BINUCLEAR COPPER(II) COMPLEX; END-TO-END; COORDINATION POLYMERS; MAGNETIC-PROPERTIES; CU(II) COMPOUNDS; CO-LIGAND; BEHAVIOR;

D O I：

10.1007/s11243-010-9439-x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three azido-bridged copper(II) complexes, [Cu-2(L-1)(2)(mu(1,1,3)-N-3)(2)](n)center dot 2nH(2)O (1), [Cu-4(L-2)(4)(mu(1,1)-N-3)(2)(mu(1,1,3)-N-3)(2)](n) (2), and [Cu-2(L-3)(2)(mu(1,1)-N-3)(2)] (3), where L-1, L-2, and L-3 are the deprotonated forms of 4-bromo-2-[(2-methylaminoethylimino)methyl]phenol (HL1), 4-bromo-2-[(2-ethylaminoethylimino)methyl]phenol (HL2), and 4-bromo-2-[(2-isopropylaminoethylimino)methyl]phenol (HL3), respectively, have been prepared and structurally characterized by single-crystal X-ray diffraction analysis and IR spectra. The slight differences in the terminal groups of the Schiff bases lead to different bridging modes of the azido groups.

引用

页码：93 / 98

页数：6

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