A step in the right direction

被引：0
作者：
Zaera, Francisco [1 ]
机构：
[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA
来源：
NATURE CHEMISTRY | 2015年 / 7卷 / 04期
关键词：
CO; ADSORPTION;
D O I：
10.1038/nchem.2217
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Identifying the contribution of different surface sites to the overall kinetics of molecular desorption from solid surfaces is difficult even when using single crystals. A new technique that combines molecular beams with UV−UV double resonance spectroscopy resolves this problem for the case of carbon monoxide on Pt(111).
引用
收藏
页码：279 / 280
页数：3
相关论文
共 9 条
  • [1] An improved single crystal adsorption calorimeter for determining gas adsorption and reaction energies on complex model catalysts
    Fischer-Wolfarth, Jan-Henrik
    Hartmann, Jens
    Farmer, Jason A.
    Flores-Camacho, J. Manuel
    Campbell, Charles T.
    Schauermann, Swetlana
    Freund, Hans-Joachim
    [J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 2011, 82 (02)
  • [2] CO Desorption from a Catalytic Surface: Elucidation of the Role of Steps by Velocity-Selected Residence Time Measurements
    Golibrzuch, Kai
    Shirhatti, Pranav R.
    Geweke, Jan
    Werdecker, Joern
    Kandratsenka, Alexander
    Auerbach, Daniel J.
    Wodtke, Alec M.
    Bartels, Christof
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (04) : 1465 - 1475
  • [3] Hoffmann R., 1988, Solids and surfaces: A chemist's view of bonding in extended structures
  • [4] Karmazyn AD, 2003, SURF SCI, V538, P171, DOI [10.1016/S0039-6028(03)00726-X, 10.1016/s0039-6028(03)00726-x]
  • [5] Isokinetic relationship, isoequilibrium relationship, and enthalpy-entropy compensation
    Liu, L
    Guo, QX
    [J]. CHEMICAL REVIEWS, 2001, 101 (03) : 673 - 695
  • [6] Thermodynamics and kinetics of CO and benzene adsorption on Pt(111) studied with pulsed molecular beams and microcalorimetry
    Schiesser, Alexander
    Hortz, Peter
    Schafer, Rolf
    [J]. SURFACE SCIENCE, 2010, 604 (23-24) : 2098 - 2105
  • [7] Somorjai G. A. L. Y, 2010, INTRO SURFACE CHEM C
  • [8] Calorimetric heats for CO and oxygen adsorption and for the catalytic CO oxidation reaction on Pt{111}
    Yeo, YY
    Vattuone, L
    King, DA
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1997, 106 (01) : 392 - 401
  • [9] Zaera F., 2013, Comprehensive Inorganic ChemistryII, P39
1