A transparent electrode with water-oxidizing activity

被引：32

作者：

Azadi, Gouhar ^{[1
]}

Bagheri, Robabeh ^{[2
]}

Bikas, Rahman ^{[3
]}

Mousazade, Younes ^{[1
]}

Cui, Junfeng ^{[4
,5
]}

Song, Zhenlun ^{[2
]}

Kinzhybalo, Vasyl ^{[6
]}

Shen, Jian-Ren ^{[7
,8
,9
]}

Allakhverdiev, Suleyman I. ^{[10
,11
,12
,13
,14
]}

Najafpour, Mohammad Mahdi ^{[1
,15
,16
]}

机构：

[1] IASBS, Dept Chem, Zanjan 4513766731, Iran

[2] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Surface Dept, Surface Protect Res Grp, 519 Zhuangshi Rd, Ningbo 315201, Zhejiang, Peoples R China

[3] Imam Khomeini Int Univ, Dept Chem, Fac Sci, Qazvin 3414896818, Iran

[4] Dalian Univ Technol, Key Lab Precis & Nontradit Machining Technol, Minist Educ, Dalian 116024, Peoples R China

[5] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Marine Mat & Related Technol, Ningbo 315201, Zhejiang, Peoples R China

[6] Polish Acad Sci, Inst Low Temp & Struct Res, PL-50422 Wroclaw, Poland

[7] Okayama Univ, Res Inst Interdisciplinary Sci, Okayama 7008530, Japan

[8] Okayama Univ, Grad Sch Nat Sci & Technol, Okayama 7008530, Japan

[9] Chinese Acad Sci, Inst Bot, Photosynth Res Ctr, Key Lab Photobiol, 20 Nanxincun, Beijing 100093, Peoples R China

[10] Russian Acad Sci, Inst Plant Physiol, Controlled Photobiosynth Lab, Bot Skaya St 35, Moscow 127276, Russia

[11] Azerbaijan Natl Acad Sci, Inst Mol Biol & Biotechnol, Bionanotechnol Lab, Matbuat Ave 2a, Baku 1073, Azerbaijan

[12] Russian Acad Sci, Inst Basic Biol Problems, Pushchino 142290, Moscow Region, Russia

[13] Moscow MV Lomonosov State Univ, Dept Plant Physiol, Fac Biol, Leninskie Gory 1-12, Moscow 119991, Russia

[14] Moscow Inst Phys & Technol, Inst Sky Lane 9, Dolgoprudnyi 141700, Moscow Region, Russia

[15] IASBS, Ctr Climate Change & Global Warming, Zanjan 4513766731, Iran

[16] IASBS, Res Ctr Basic Sci & Modern Technol RBST, Zanjan 4513766731, Iran

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2018年 / 43卷 / 51期

基金：

俄罗斯科学基金会; 美国国家科学基金会;

关键词：

Water oxidation; Hydrogen production; Fluorine-doped tin oxide; Catalyst; OXIDATION CATALYSTS; SINGLE-CRYSTALS; MANGANESE OXIDE; NICKEL; COMPLEX; EFFICIENT; TETRAFLUOROBORATE; ELECTROCATALYSTS; PALLADIUM; INSIGHTS;

D O I：

10.1016/j.ijhydene.2018.10.146

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrogen production by water splitting is a promising method to store energy. Water-oxidation reaction is a bottleneck in water-splitting systems. Herein, a mononuclear nickel(II) phosphine complex with 1,2-bis(dicyclohexylphosphino)ethane ligand, was synthesized and characterized by X-ray crystallography method. The water-oxidizing catalyst under the electrochemical condition was studied. The role of Ni compound for the water-oxidation reaction on the surface of fluorine-doped tin oxide as one of the true catalysts was investigated by the electrochemical methods and Scanning Electron Microscopy coupled with Energy Dispersive X-ray (SEM/EDX) Spectroscopy. The big ligand around the Ni ion causes a very small size of Ni-based particles on the surface of the electrode, which are the active catalysts for the water-oxidation reaction. Such small nanosized Ni-based compounds are transparent and have no effect on the transparency of the obtained fluorine-doped tin oxide. Thus, it is a promising method to synthesize a transparent fluorine-doped tin oxide with water-oxidizing activity. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：22896 / 22904

页数：9

共 59 条

[51] Solid- State Interconversions: Unique 100% Reversible Transformations between the Ground and Metastable States in Single- Crystals of a Series of Nickel( II) Nitro Complexes
Warren, Mark R.
Easun, Timothy L.
Brayshaw, Simon K.
Deeth, Robert J.
George, Michael W.
Johnson, Andrew L.
Schiffers, Stefanie
Teat, Simon J.
Warren, Anna J.
Warren, John E.
Wilson, Chick C.
Woodall, Christopher H.
Raithby, Paul R.
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (18) : 5468 - 5477
[52] Photoactivated linkage isomerism in single crystals of nickel, palladium and platinum di-nitro complexes - a photocrystallographic investigation
Warren, Mark R.
Brayshaw, Simon K.
Hatcher, Lauren E.
Johnson, Andrew L.
Schiffers, Stefanie
Warren, Anna J.
Teat, Simon J.
Warren, John E.
Woodall, Christopher H.
Raithby, Paul R.
[J]. DALTON TRANSACTIONS, 2012, 41 (42) : 13173 - 13179
[53] Wells NP, 2002, J PHYS CHEM A, V106, P1518, DOI [10.1021/jp013261j, 10.1021/jp01326lj]
[54] Water oxidation catalysis by manganese oxides: learning from evolution
Wiechen, M.
Najafpour, M. M.
Allakhverdiev, S. I.
Spiccia, L.
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (07) : 2203 - 2212
[55] Molecular catalysts for water oxidation
Yagi, M
Kaneko, M
[J]. CHEMICAL REVIEWS, 2001, 101 (01) : 21 - 35
[56] Photosynthetic Water Oxidation: Insights from Manganese Model Chemistry
Young, Karin J.
Brennan, Bradley J.
Tagore, Ranitendranath
Brudvig, Gary W.
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2015, 48 (03) : 567 - 574
[57] Synthesis and characterization of non-chelating ruthenium-indenylidene olefin metathesis catalysts derived from substituted 1,1-diphenyl-2-propyn-1-ols
Yu, Baoyi
Xie, Yu
Hamad, Fatma B.
Leus, Karen
Lyapkov, Alex A.
Van Hecke, Kristof
Verpoort, Francis
[J]. NEW JOURNAL OF CHEMISTRY, 2015, 39 (03) : 1858 - 1867
[58] Influence of steric hindrance on the molecular packing and the anchoring of quinonoid zwitterions on gold surfaces
Yuan, Minghui
Tanabe, Iori
Bernard-Schaaf, Jean-Marie
Shi, Qin-Yin
Schlegel, Vicki
Schurhammer, Rachel
Dowben, Peter A.
Doudin, Bernard
Routaboul, Lucie
Braunstein, Pierre
[J]. NEW JOURNAL OF CHEMISTRY, 2016, 40 (07) : 5782 - 5796
[59] Zhang M, 2014, ANGEW CHEM, V126, P13258

← 1 2 3 4 5 6 →