A transparent electrode with water-oxidizing activity

被引：32
作者：
Azadi, Gouhar [1 ]
Bagheri, Robabeh [2 ]
Bikas, Rahman [3 ]
Mousazade, Younes [1 ]
Cui, Junfeng [4 ,5 ]
Song, Zhenlun [2 ]
Kinzhybalo, Vasyl [6 ]
Shen, Jian-Ren [7 ,8 ,9 ]
Allakhverdiev, Suleyman I. [10 ,11 ,12 ,13 ,14 ]
Najafpour, Mohammad Mahdi [1 ,15 ,16 ]
机构：
[1] IASBS, Dept Chem, Zanjan 4513766731, Iran
[2] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Surface Dept, Surface Protect Res Grp, 519 Zhuangshi Rd, Ningbo 315201, Zhejiang, Peoples R China
[3] Imam Khomeini Int Univ, Dept Chem, Fac Sci, Qazvin 3414896818, Iran
[4] Dalian Univ Technol, Key Lab Precis & Nontradit Machining Technol, Minist Educ, Dalian 116024, Peoples R China
[5] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Marine Mat & Related Technol, Ningbo 315201, Zhejiang, Peoples R China
[6] Polish Acad Sci, Inst Low Temp & Struct Res, PL-50422 Wroclaw, Poland
[7] Okayama Univ, Res Inst Interdisciplinary Sci, Okayama 7008530, Japan
[8] Okayama Univ, Grad Sch Nat Sci & Technol, Okayama 7008530, Japan
[9] Chinese Acad Sci, Inst Bot, Photosynth Res Ctr, Key Lab Photobiol, 20 Nanxincun, Beijing 100093, Peoples R China
[10] Russian Acad Sci, Inst Plant Physiol, Controlled Photobiosynth Lab, Bot Skaya St 35, Moscow 127276, Russia
[11] Azerbaijan Natl Acad Sci, Inst Mol Biol & Biotechnol, Bionanotechnol Lab, Matbuat Ave 2a, Baku 1073, Azerbaijan
[12] Russian Acad Sci, Inst Basic Biol Problems, Pushchino 142290, Moscow Region, Russia
[13] Moscow MV Lomonosov State Univ, Dept Plant Physiol, Fac Biol, Leninskie Gory 1-12, Moscow 119991, Russia
[14] Moscow Inst Phys & Technol, Inst Sky Lane 9, Dolgoprudnyi 141700, Moscow Region, Russia
[15] IASBS, Ctr Climate Change & Global Warming, Zanjan 4513766731, Iran
[16] IASBS, Res Ctr Basic Sci & Modern Technol RBST, Zanjan 4513766731, Iran
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2018年 / 43卷 / 51期
基金：
美国国家科学基金会; 俄罗斯科学基金会;
关键词：
Water oxidation; Hydrogen production; Fluorine-doped tin oxide; Catalyst; OXIDATION CATALYSTS; SINGLE-CRYSTALS; MANGANESE OXIDE; NICKEL; COMPLEX; EFFICIENT; TETRAFLUOROBORATE; ELECTROCATALYSTS; PALLADIUM; INSIGHTS;
D O I：
10.1016/j.ijhydene.2018.10.146
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Hydrogen production by water splitting is a promising method to store energy. Water-oxidation reaction is a bottleneck in water-splitting systems. Herein, a mononuclear nickel(II) phosphine complex with 1,2-bis(dicyclohexylphosphino)ethane ligand, was synthesized and characterized by X-ray crystallography method. The water-oxidizing catalyst under the electrochemical condition was studied. The role of Ni compound for the water-oxidation reaction on the surface of fluorine-doped tin oxide as one of the true catalysts was investigated by the electrochemical methods and Scanning Electron Microscopy coupled with Energy Dispersive X-ray (SEM/EDX) Spectroscopy. The big ligand around the Ni ion causes a very small size of Ni-based particles on the surface of the electrode, which are the active catalysts for the water-oxidation reaction. Such small nanosized Ni-based compounds are transparent and have no effect on the transparency of the obtained fluorine-doped tin oxide. Thus, it is a promising method to synthesize a transparent fluorine-doped tin oxide with water-oxidizing activity. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：22896 / 22904
页数：9
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