Influence of the Hydro/Fluorocarbon Chain Length on CMC and HLB of Surface-Active Nonionic Surfactants Containing Polyethylene Glycol Groups

被引：5
|
作者：
Khalfallah, Ali [1 ,2 ]
Kriaa, Abdelkader [3 ]
Hedhli, Ahmed [3 ]
机构：
[1] Univ Gabes, IPEIG, Gabes, Tunisia
[2] Univ Gabes, Higher Sch Sci & Tech Tunis, Chem, Gabes, Tunisia
[3] Univ Tunis, Higher Sch Sci & Tech Tunis, Chem, Tunis, Tunisia
来源：
TENSIDE SURFACTANTS DETERGENTS | 2018年 / 55卷 / 03期
关键词：
Surfactant; critical micelle concentration (CMC); hydrophilic-lipophilic balance (HLB); fluorine; AQUEOUS-SOLUTIONS; ETHERS; ACID; HEADGROUPS; CATION;
D O I：
10.3139/113.110560
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Series of cyclic polyethylene glycol succinates based surfactants bearing a hydro- or fluorocarbon group was synthesized and characterized. Evaluation of the surface-active properties of the obtained compounds reveals, (i) the surface tension decreases gradually when is the length of the lipophilic chain increased (ii) the critical micelle concentration (CMC) increases with the number of ethylene oxide unit present in the polar head and (iii) surface tension follows the increasing pattern of hydrophilic-lipophilic balance (HLB) number.
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页码：246 / 251
页数：6
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