Catalytic asymmetric hydrophosphonylation of ynones

被引：57

作者：

Uraguchi, Daisuke ^{[1
]}

Ito, Takaki ^{[1
]}

Nakamura, Shinji ^{[1
]}

Ooi, Takashi ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Chikusa Ku, Nagoya, Aichi 4648603, Japan

来源：

CHEMICAL SCIENCE | 2010年 / 1卷 / 04期

关键词：

ALPHA-HYDROXY PHOSPHONATES; HIGHLY ENANTIOSELECTIVE HYDROPHOSPHONYLATION; DIRECT HENRY REACTION; PHOSPHATE-REARRANGEMENT; NITROALDOL REACTION; ADDITION-REACTIONS; ALDEHYDES; KETONES; ESTERS; HYDROXYPHOSPHONATES;

D O I：

10.1039/c0sc00268b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic, highly enantioselective hydrophosphonylation of ynones has been achieved by exploiting the characteristic features of in situ generated chiral tetraaminophosphonium phosphite.

引用

页码：488 / 490

页数：3

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