Synthesis, Applications, and Prospects of Graphene Quantum Dots: A Comprehensive Review

被引:277
作者
Ghaffarkhah, Ahmadreza [1 ]
Hosseini, Ehsan [1 ]
Kamkar, Milad [1 ]
Sehat, Ali Akbari [1 ]
Dordanihaghighi, Sara [1 ]
Allahbakhsh, Ahmad [2 ]
van der Kuur, Colin [3 ]
Arjmand, Mohammad [1 ]
机构
[1] Univ British Columbia, Sch Engn, Nanomat & Polymer Nanocomposites Lab, Kelowna, BC V1V 1V7, Canada
[2] Hakim Sabzevari Univ, Fac Engn, Dept Mat & Polymer Engn, Sabzevar, Iran
[3] ZEN Graphene Solut, 210-1205 Amber Dr, Thunder Bay, ON P7B 6M4, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
biomedical applications; energy-related applications; graphene quantum dots; sensing; BOTTOM-UP FABRICATION; LIGHT-EMITTING-DIODES; MICROWAVE-ASSISTED SYNTHESIS; SENSITIZED SOLAR-CELLS; PULSED-LASER ABLATION; LITHIUM-ION BATTERIES; N-CODOPED GRAPHENE; ONE-POT SYNTHESIS; HEAVY-METAL IONS; FACILE SYNTHESIS;
D O I
10.1002/smll.202102683
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Graphene quantum dot (GQD) is one of the youngest superstars of the carbon family. Since its emergence in 2008, GQD has attracted a great deal of attention due to its unique optoelectrical properties. Non-zero bandgap, the ability to accommodate functional groups and dopants, excellent dispersibility, highly tunable properties, and biocompatibility are among the most important characteristics of GQDs. To date, GQDs have displayed significant momentum in numerous fields such as energy devices, catalysis, sensing, photodynamic and photothermal therapy, drug delivery, and bioimaging. As this field is rapidly evolving, there is a strong need to identify the emerging challenges of GQDs in recent advances, mainly because some novel applications and numerous innovations on the ease of synthesis of GQDs are not systematically reviewed in earlier studies. This feature article provides a comparative and balanced discussion of recent advances in synthesis, properties, and applications of GQDs. Besides, current challenges and future prospects of these emerging carbon-based nanomaterials are also highlighted. The outlook provided in this review points out that the future of GQD research is boundless, particularly if upcoming studies focus on the ease of purification and eco-friendly synthesis along with improving the photoluminescence quantum yield and production yield of GQDs.
引用
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页数:48
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共 506 条
[51]   Unique properties of graphene quantum dots and their applications in photonic/electronic devices [J].
Choi, Suk-Ho .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2017, 50 (10)
[52]   The in vitro and in vivo toxicity of graphene quantum dots [J].
Chong, Yu ;
Ma, Yufei ;
Shen, He ;
Tu, Xiaolong ;
Zhou, Xuan ;
Xu, Jiaying ;
Dai, Jianwu ;
Fan, Saijun ;
Zhang, Zhijun .
BIOMATERIALS, 2014, 35 (19) :5041-5048
[53]   Optical properties of few layered graphene quantum dots [J].
Choudhary, Raghvendra Pratap ;
Shukla, Shobha ;
Vaibhav, Kumar ;
Pawar, Pranav Bhagwan ;
Saxena, Sumit .
MATERIALS RESEARCH EXPRESS, 2015, 2 (09)
[54]   Highly Sensitive and Selective Detection of Nanomolar Ferric Ions Using Dopamine Functionalized Graphene Quantum Dots [J].
Chowdhury, Ankan Dutta ;
Doong, Ruey-an .
ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (32) :21002-21010
[55]   Synthesis of Strongly Fluorescent Graphene Quantum Dots by Cage-Opening Buckminsterfullerene [J].
Chua, Chun Kiang ;
Sofer, Zdenek ;
Simek, Petr ;
Jankovsky, Ondrej ;
Klimova, Katerina ;
Bakardjieva, Snejana ;
Kuckova, Stepanka Hrdlickova ;
Pumera, Martin .
ACS NANO, 2015, 9 (03) :2548-2555
[56]   Graphene oxide as surfactant sheets [J].
Cote, Laura J. ;
Kim, Jaemyung ;
Tung, Vincent C. ;
Luo, Jiayan ;
Kim, Franklin ;
Huang, Jiaxing .
PURE AND APPLIED CHEMISTRY, 2011, 83 (01) :95-110
[57]   Toward N-Doped Graphene via Solvothermal Synthesis [J].
Deng, Dehui ;
Pan, Xiulian ;
Yu, Liang ;
Cui, Yi ;
Jiang, Yeping ;
Qi, Jing ;
Li, Wei-Xue ;
Fu, Qiang ;
Ma, Xucun ;
Xue, Qikun ;
Sun, Gongquan ;
Bao, Xinhe .
CHEMISTRY OF MATERIALS, 2011, 23 (05) :1188-1193
[58]   Large scale preparation of graphene quantum dots from graphite oxide in pure water via one-step electrochemical tailoring [J].
Deng, Jianhui ;
Lu, Qiujun ;
Li, Haitao ;
Zhang, Youyu ;
Yao, Shouzuo .
RSC ADVANCES, 2015, 5 (38) :29704-29707
[59]   PEI modified multiwalled carbon nanotube as a novel additive in PAN nanofiber membrane for enhanced removal of heavy metal ions [J].
Deng, Sheng ;
Liu, Xinhui ;
Liao, Jianbo ;
Lin, Hui ;
Liu, Fang .
CHEMICAL ENGINEERING JOURNAL, 2019, 375
[60]   Graphene Quantum Dot-Sensitized ZnO Nanorod/Polymer Schottky Junction UV Detector with Superior External Quantum Efficiency, Detectivity, and Responsivity [J].
Dhar, Saurab ;
Majumder, Tanmoy ;
Mondal, Suvra Prakash .
ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (46) :31822-31831