Synthesis, Applications, and Prospects of Graphene Quantum Dots: A Comprehensive Review

被引:277
作者
Ghaffarkhah, Ahmadreza [1 ]
Hosseini, Ehsan [1 ]
Kamkar, Milad [1 ]
Sehat, Ali Akbari [1 ]
Dordanihaghighi, Sara [1 ]
Allahbakhsh, Ahmad [2 ]
van der Kuur, Colin [3 ]
Arjmand, Mohammad [1 ]
机构
[1] Univ British Columbia, Sch Engn, Nanomat & Polymer Nanocomposites Lab, Kelowna, BC V1V 1V7, Canada
[2] Hakim Sabzevari Univ, Fac Engn, Dept Mat & Polymer Engn, Sabzevar, Iran
[3] ZEN Graphene Solut, 210-1205 Amber Dr, Thunder Bay, ON P7B 6M4, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
biomedical applications; energy-related applications; graphene quantum dots; sensing; BOTTOM-UP FABRICATION; LIGHT-EMITTING-DIODES; MICROWAVE-ASSISTED SYNTHESIS; SENSITIZED SOLAR-CELLS; PULSED-LASER ABLATION; LITHIUM-ION BATTERIES; N-CODOPED GRAPHENE; ONE-POT SYNTHESIS; HEAVY-METAL IONS; FACILE SYNTHESIS;
D O I
10.1002/smll.202102683
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Graphene quantum dot (GQD) is one of the youngest superstars of the carbon family. Since its emergence in 2008, GQD has attracted a great deal of attention due to its unique optoelectrical properties. Non-zero bandgap, the ability to accommodate functional groups and dopants, excellent dispersibility, highly tunable properties, and biocompatibility are among the most important characteristics of GQDs. To date, GQDs have displayed significant momentum in numerous fields such as energy devices, catalysis, sensing, photodynamic and photothermal therapy, drug delivery, and bioimaging. As this field is rapidly evolving, there is a strong need to identify the emerging challenges of GQDs in recent advances, mainly because some novel applications and numerous innovations on the ease of synthesis of GQDs are not systematically reviewed in earlier studies. This feature article provides a comparative and balanced discussion of recent advances in synthesis, properties, and applications of GQDs. Besides, current challenges and future prospects of these emerging carbon-based nanomaterials are also highlighted. The outlook provided in this review points out that the future of GQD research is boundless, particularly if upcoming studies focus on the ease of purification and eco-friendly synthesis along with improving the photoluminescence quantum yield and production yield of GQDs.
引用
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页数:48
相关论文
共 506 条
[41]   Unusual emission transformation of graphene quantum dots induced by self-assembled aggregation [J].
Chen, Shuai ;
Liu, Jia-Wei ;
Chen, Mei-Ling ;
Chen, Xu-Wei ;
Wang, Jian-Hua .
CHEMICAL COMMUNICATIONS, 2012, 48 (61) :7637-7639
[42]   A facile photoluminescence modulated nanosensor based on nitrogen-doped graphene quantum dots for sulfite detection [J].
Chen, Shufan ;
Song, Yu ;
Li, Yang ;
Liu, Yunling ;
Su, Xingguang ;
Ma, Qiang .
NEW JOURNAL OF CHEMISTRY, 2015, 39 (10) :8114-8120
[43]   Optical properties of fluorescent zigzag graphene quantum dots derived from multi-walled carbon nanotubes [J].
Chen, Wei ;
Li, Fushan ;
Wu, Chaoxing ;
Guo, Tailiang .
APPLIED PHYSICS LETTERS, 2014, 104 (06)
[44]   Synthesis and applications of graphene quantum dots: a review [J].
Chen, Weifeng ;
Lv, Guo ;
Hu, Weimin ;
Li, Dejiang ;
Chen, Shaona ;
Dai, Zhongxu .
NANOTECHNOLOGY REVIEWS, 2018, 7 (02) :157-185
[45]   Phase Behavior of Pickering Emulsions Stabilized by Graphene Oxide Sheets and Resins [J].
Chen, Xi ;
Song, Xinmin ;
Huang, Jia ;
Wu, Chaodong ;
Ma, Desheng ;
Tian, Maozhang ;
Jiang, Hang ;
Huang, Pei .
ENERGY & FUELS, 2017, 31 (12) :13439-13447
[46]   Minimization of Ion-Solvent Clusters in Gel Electrolytes Containing Graphene Oxide Quantum Dots for Lithium-Ion Batteries [J].
Chen, Yen-Ming ;
Hsu, Shih-Ting ;
Tseng, Yu-Hsien ;
Yeh, Te-Fu ;
Hou, Sheng-Shu ;
Jan, Jeng-Shiung ;
Lee, Yuh-Lang ;
Teng, Hsisheng .
SMALL, 2018, 14 (12)
[47]   Graphene quantum dots modified nanoporous SiAl composite as an advanced anode for lithium storage [J].
Chen, Zizhong ;
Hou, Jiagang ;
Liu, Qiang ;
Zhou, Qiuxia ;
Liu, Hong ;
Xu, Caixia .
ELECTROCHIMICA ACTA, 2019, 318 :228-235
[48]   Highly Stretchable and Sensitive Photodetectors Based on Hybrid Graphene and Graphene Quantum Dots [J].
Chiang, Chia-Wei ;
Haider, Golam ;
Tan, Wei-Chun ;
Liou, Yi-Rou ;
Lai, Ying-Chih ;
Ravindranath, Rini ;
Chang, Huan-Tsung ;
Chen, Yang-Fang .
ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (01) :466-471
[49]   Surface Engineering of Graphene Quantum Dots and Their Applications as Efficient Surfactants [J].
Cho, Han-Hee ;
Yang, Hyunseung ;
Kang, Dong Jin ;
Kim, Bumjoon J. .
ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (16) :8615-8621
[50]  
Choi S.U.S., 1995, Enhancing thermal conductivity of fluids with nanoparticles, P99