Selective Extraction and Complexation Studies for Thorium(IV) with Bis-triamide Extractants: Synthesis, Solvent Extraction, EXAFS, and DFT

Three octyl-extended bis-triamide extractants (L1-L3) were designed and synthesized for the selective solvent extraction of Th(IV) over U(VI) in a kerosene-HNO3 system. L1 and L2 exhibited good extraction property and selectivity toward Th(IV) over U(VI) and reached extraction equilibrium within 10 min. In a wide range of a HNO3 concentration from 0.1 to 3.0 M, the separation factor of Th(IV) over U(VI) (SFTh/U) of L1 and L2 ranged from 12.1 +/- 1.6 to 123.0 +/- 20.2 and 15.2 +/- 2.4 to 88.1 +/- 14.9, respectively. Slope analysis indicated that Th(IV) was extracted as different species under different HNO3 concentrations, in which the slopes were 2.08 +/- 0.20, 1.61 +/- 0.03, and 1.54 +/- 0.03 for L1 and 2.37 +/- 0.22, 2.07 +/- 0.17, and 1.76 +/- 0.18 for L2 under 0.1, 1.0, and 3.0 M HNO3, respectively. A continuous variation method (Job plot) illustrated a 1.5:1 ligand/thorium (L/Th) ratio in a methanol phase, indicating that L1/L2 and Th(IV) could form mixed 1:1 and 2:1 L/Th extracted complexes. Extended X-ray absorption fine structure (EXAFS) and density functional theory (DFT) calculations revealed that the extracted complexes of L1 and L2 with Th during the extraction process at 0.1 M HNO3 were [2L1 center dot Th center dot 3(NO3)](+) and [2L2 center dot Th center dot 3(NO3)](+).