(Bromodimethyl)sulfonium Bromide-Mediated Thiolysis of Epoxides: An Easy Access to -Hydroxy Sulfides and Benzoxathiepinones in Solvent-Free Conditions

被引：9
|
作者：
Shailaja, M. [1 ]
Manjula, A. [1 ]
Rao, B. Vittal [1 ]
机构：
[1] Indian Inst Chem Technol, Organ Chem Div 2, Hyderabad 500607, Andhra Pradesh, India
来源：
SYNTHETIC COMMUNICATIONS | 2010年 / 40卷 / 24期
关键词：
(Bromodimethyl)sulfonium bromide; epoxides; -hydroxy sulfides; solvent-free reactions; thiols;
D O I：
10.1080/00397910903458595
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A mild, rapid and highly regioselective opening of epoxides by mercaptans to -hydroxy sulfides and benzoxathiepinones has been achieved in excellent yields, using catalytic amount of (bromodimethyl)sulfonium bromide in solvent free reaction conditions.
引用
收藏
页码：3629 / 3639
页数：11
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