Novel Nonanol-Based deep eutectic solvents: Thermophysical properties and their applications in Liquid-Liquid extraction and amino acid detection

被引:33
|
作者
Omar, Karzan A. [1 ,2 ]
Sadeghi, Rahmat [1 ]
机构
[1] Univ Kurdistan, Dept Chem, Sanandaj, Iran
[2] Koya Univ, Fac Sci & Hlth, Dept Chem, Koya KOY45, Kurdistan Regio, Iraq
关键词
Hydrophobic deep eutectic solvents; Congo red; Potassium permanganate; Potassium dichromate; Removal; Amino acid detection; CHOLINE-CHLORIDE; LEVULINIC ACID; BASIC DYE; REMOVAL; TEMPERATURE; ADSORPTION; DESS;
D O I
10.1016/j.molliq.2021.116359
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, novel nonanol-based deep eutectic solvents (DESs) were synthesized from the various ammonium salts as hydrogen bond acceptors (HBAs) in a combination with 1-nonanol as a hydrogen bond donor (HBD). The synthesized hydrophobic DESs were characterized by measuring their physical properties including density, sound velocity, viscosity, electrical conductivity, surface tension, and refractive index as a function of temperature. Furthermore, a new method based on the prepared DESs was introduced for removal of Congo red, KMnO4, and K2Cr2O7 from aqueous solutions with 100% efficiency, during 45-60 min of removal processes. Furthermore, one of the synthesized DESs was applied as qualitative and quantitative indicator for alanine, leucine, serine, glutamine, methionine, and glycine amino acids by spectrophotometry method. (C) 2021 Elsevier B.V. All rights reserved.
引用
收藏
页数:11
相关论文
共 50 条
  • [21] Enantioseparation of ofloxacin using a liquid-liquid extraction system based on hydrophobic eutectic solvents
    Moradi, Mahtab
    Ferreira, Ana M.
    Neves, Catarina M. S. S.
    Sosa, Filipe H. B.
    Pazuki, Gholamreza
    Coutinho, Joao A. P.
    SEPARATION AND PURIFICATION TECHNOLOGY, 2025, 353
  • [22] Novel ninhydrin-based deep eutectic solvents for amino acid detection
    Omar, Karzan A.
    Sadeghi, Rahmat
    JOURNAL OF MOLECULAR LIQUIDS, 2020, 303
  • [23] Partitioning of acai anthocyanins using liquid-liquid equilibrium based on deep eutectic solvents
    Moreno, Adriana M.
    da Silva, Izadora R.
    Andrade, Elisangela
    Pelaquim, Fernanda P.
    da Costa, Mariana C.
    dos Santos, Geormenny R.
    BRAZILIAN JOURNAL OF CHEMICAL ENGINEERING, 2024, 41 (01) : 569 - 584
  • [24] Synthesis and application of magnetic deep eutectic solvents: Novel solvents for ultrasound assisted liquid-liquid microextraction of thiophene
    Khezeli, Tahere
    Daneshfar, Ali
    ULTRASONICS SONOCHEMISTRY, 2017, 38 : 590 - 597
  • [25] Characterization of Deep Eutectic Solvents for Dispersive Liquid-Liquid Microextraction for Phenolics
    Ma, Wanwan
    Tang, Weiyang
    Row, Kyung Ho
    ANALYTICAL LETTERS, 2017, 50 (14) : 2177 - 2188
  • [26] Liquid-liquid extraction of phenolic compounds from aqueous solution using hydrophobic deep eutectic solvents
    Cable, Pierre-Alann
    Le Brech, Yann
    Mutelet, Fabrice
    JOURNAL OF MOLECULAR LIQUIDS, 2022, 366
  • [27] Extraction Process of Amino Acids with Deep Eutectic Solvents-Based Supported Liquid Membranes
    Li, Zhuo
    Cui, Yingna
    Shen, Yongming
    Li, Changping
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2018, 57 (12) : 4407 - 4419
  • [28] Liquid-liquid microextraction techniques based on in-situ formation/decomposition of deep eutectic solvents
    Ahmadi, Raheleh
    Azooz, Ebaa Adnan
    Yamini, Yadollah
    Ramezani, Amir M.
    TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2023, 161
  • [29] A Review of the Use of Eutectic Solvents, Terpenes and Terpenoids in Liquid-liquid Extraction Processes
    Rodriguez-Llorente, Diego
    Canada-Barcala, Andres
    Alvarez-Torrellas, Silvia
    Ismael Agueda, Vicente
    Garcia, Juan
    Larriba, Marcos
    PROCESSES, 2020, 8 (10) : 1 - 54
  • [30] Acid induced dispersive liquid-liquid microextraction based on in situ formation of hydrophobic deep eutectic solvents for the extraction of bisphenol A and alkylphenols in water and beverage samples
    Zhang, Kaige
    Wang, Jing
    Guo, Rong
    Nie, Qiujun
    Zhu, Guifen
    FOOD CHEMISTRY, 2024, 442