Defect-mediated emulsification in two dimensions

被引:20
作者
Korolev, K. S. [1 ]
Nelson, David R. [1 ]
机构
[1] Harvard Univ, Dept Phys, Cambridge, MA 02138 USA
来源
PHYSICAL REVIEW E | 2008年 / 77卷 / 05期
基金
美国国家科学基金会;
关键词
D O I
10.1103/PhysRevE.77.051702
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We consider two-dimensional dispersions of droplets of isotropic phase in a liquid with an XY-like order parameter, tilt, nematic, and hexatic symmetries being included. Strong anchoring boundary conditions are assumed. Textures for a single droplet and a pair of droplets are calculated and a universal droplet-droplet pair potential is obtained. The interaction of dispersed droplets via the ordered phase is attractive at large distances and repulsive at short distances, which results in a well defined preferred separation for two droplets and topological stabilization of the emulsion. This interaction also drives self-assembly into chains. Preferred separations and energy barriers to coalescence are calculated, and the effects of thermal fluctuations and film thickness are discussed.
引用
收藏
页数:11
相关论文
共 37 条
[1]   PHASE-TRANSITIONS IN LANGMUIR MONOLAYERS OF POLAR-MOLECULES [J].
ANDELMAN, D ;
BROCHARD, F ;
JOANNY, JF .
JOURNAL OF CHEMICAL PHYSICS, 1987, 86 (06) :3673-3681
[2]   Cellular solid behaviour of liquid crystal colloids - 1. Phase separation and morphology [J].
Anderson, VJ ;
Terentjev, EM ;
Meeker, SP ;
Crain, J ;
Poon, WCK .
EUROPEAN PHYSICAL JOURNAL E, 2001, 4 (01) :11-20
[3]   Imaging coexisting fluid domains in biomembrane models coupling curvature and line tension [J].
Baumgart, T ;
Hess, ST ;
Webb, WW .
NATURE, 2003, 425 (6960) :821-824
[4]   Large-scale fluid/fluid phase separation of proteins and lipids in giant plasma membrane vesicles [J].
Baumgart, Tobias ;
Hammond, Adam T. ;
Sengupta, Prabuddha ;
Hess, Samuel T. ;
Holowka, David A. ;
Baird, Barbara A. ;
Webb, Watt W. .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2007, 104 (09) :3165-3170
[5]   SUPERFLUIDITY AND PHASE-SEPARATION IN HELIUM FILMS [J].
BERKER, AN ;
NELSON, DR .
PHYSICAL REVIEW B, 1979, 19 (05) :2488-2503
[6]   Energetics of 2D colloids in free-standing smectic-C films [J].
Bohley, C. ;
Stannarius, R. .
EUROPEAN PHYSICAL JOURNAL E, 2006, 20 (03) :299-308
[7]   New hexatic liquid phase observed in lyotropic thin films [J].
Chao, CY ;
Hsu, MT ;
Hsieh, WJ ;
Ho, JT ;
Lin, IJB .
PHYSICAL REVIEW LETTERS, 2004, 93 (24)
[8]  
CHIANG HT, 1995, J PHYS II, V5, P835, DOI 10.1051/jp2:1995168
[9]   Self-organization of N* inclusions in SmC* free-standing films [J].
Cluzeau, P ;
Bonnand, V ;
Joly, G ;
Dolganov, V ;
Nguyen, HT .
EUROPEAN PHYSICAL JOURNAL E, 2003, 10 (03) :231-240
[10]   Interactions between colloidal inclusions in two-dimensional smectic-C* films [J].
Cluzeau, P. ;
Poulin, P. ;
Joly, G. ;
Nguyen, H.T. .
Physical Review E - Statistical, Nonlinear, and Soft Matter Physics, 2001, 63 (3 I) :031702-031702