Effects of Fe2O3 doping on the microstructure and piezoelectric properties of 0.55Pb (Ni1/3Nb2/3)O3-0.45Pb(Zr0.3Ti0.7)O3 ceramics

被引:42
作者
Du, Jianzhou [1 ]
Qiu, Jinhao [1 ]
Zhu, Kongjun [1 ]
Ji, Hongli [1 ]
Pang, Xuming [1 ]
Luo, Jun [1 ]
机构
[1] Nanjing Univ Aeronaut & Astronaut, State Key Lab Mech & Control Mech Struct, Nanjing 210016, Peoples R China
关键词
Fe2O3; doping; 0.55PNN-0.45PZT; Ceramics; Microstructure; Electrical properties; ELECTROMECHANICAL PROPERTIES; DIELECTRIC-PROPERTIES; IRON;
D O I
10.1016/j.matlet.2011.08.038
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
0.55Pb(Ni1/3Nb2/3)O-3-0.45Pb(Zr0.3Ti0.7)O-3(PNN-PZT) ceramics with different concentration of xFe(2)O(3) doping (where x = 0.0, 0.8, 1.2, 1.6 mol%) were synthesized by the conventional solid state sintering technique. X-ray diffraction analysis reveals that all specimens are a pure perovskite phase without pyrochlore phase. The density and grain size of Fe-doped ceramics tend to increase slightly with increasing concentration of Fe2O3. Comparing with the undoped ceramics, the piezoelectric, ferroelectric and dielectric properties of the Fe-doped PNN-PZT specimens are significantly improved. Properties of the piezoelectric constant as high as d(33)-956 pC/N, the electromechanical coupling factor k(p) similar to 0.74, and the dielectric constant epsilon(r) similar to 6095 are achieved for the specimen with 1.2 mol% Fe2O3 doping sintered at 1200 degrees C for 2 h. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:153 / 155
页数:3
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