Synthesis and characterisation of a new pyridinium salt/crown ether complex and its self-assembly

被引：16
作者：
Li, Jiang-Sheng
Chen, Li-Gong [1 ]
Zhang, Ying-Ying
Xu, Yan-Jie
Deng, Yi
Zeng, Tao
Huang, Peng-Mian
机构：
[1] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
[2] Tianjin Univ, Coll Pharmaceut Sci & Technol, Tianjin 300072, Peoples R China
来源：
JOURNAL OF CHEMICAL RESEARCH | 2007年 / 06期
关键词：
polyrotaxane; charge-transfer interaction; hydrogen-bonding; 4,4'-bipyridinium cation; DB24C8;
D O I：
10.3184/030823407X225482
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The monoprotonated bipyridinium cation can complex with dibenzo-24-crown-8 by means of ion-dipole and charge-transfer interactions. They both thread to form a [2]pseudorotaxane-like complex for further intercomplex association to produce pseuclopolyrotaxane arrays through N+-H center dot center dot center dot N hydrogen bonding in the solid state.
引用
收藏
页码：350 / 352
页数：3
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