Superconductivity of Fullerides AnHgxC60 (A = K,Rb,Cs; n = 2,3) Synthesized from Amalgams

被引：7
|
作者：
Bulychev, B. M. [1 ]
Kulbachinskii, V. A. [1 ]
Lunin, R. A. [1 ]
Kytin, V. G. [1 ]
Velikodny, Yu. A. [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Moscow 119991, Russia
来源：
FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES | 2010年 / 18卷 / 4-6期
关键词：
Amalgams; EPR; Fulleride; Superconductivity; X-ray; C-60; RB;
D O I：
10.1080/1536383X.2010.487435
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The fullerides A(n)Hg(x)C(60) (A - K,Rb,Cs; n - 2,3; x<1) have been synthesized by a new method using liquid alloys of metals with mercury (amalgams). It was found that the fulleride K2HgxC60 is superconductor with transition temperature T-c = 22 K that exceeds T-c for K3C60 (19 K). The fulleride K3HgxC60 is not superconductor and has monoclinic crystal lattice. The fullerides RbnHgxC60 (n = 2,3) are superconductors with T-c = 24-25 K that is less than T-c = 28 K for Rb3C60. The fullerides with composition CsnHgxC60 (n = 2,3) are not superconductors and crystallize in orthorhombic lattices. The density of electronic states at Fermi energy was estimated from EPR data.
引用
收藏
页码：381 / 385
页数：5
相关论文
共 50 条
  • [41] Synthesis, characterization and morphotropic transitions in a family of M[(UO2)(CH3COO)3](H2O)n (M = Na, K, Rb, Cs; n=0-1.0) compounds
    Kornyakov, Ilya, V
    Kalashnikova, Sophia A.
    Gurzhiy, Vladislav V.
    Britvin, Sergey N.
    Belova, Elena, V
    Krivovichev, Sergey, V
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS, 2020, 235 (03): : 95 - 103
  • [42] Comparative Study of M[N(SO2F)(SO2CF3)]-[N-Butyl-N-methylpyrroridinium][N(SO2F)(SO2CF3)] (M = Li, Na, K, Rb, Cs) Ionic Liquid Electrolytes
    Yamamoto, Takayuki
    Nishijima, Shu
    Nohira, Toshiyuki
    JOURNAL OF PHYSICAL CHEMISTRY B, 2020, 124 (38): : 8380 - 8387
  • [43] CRYSTALLOGRAPHIC CHARACTERIZATION OF LIMPO3F TYPE FLUOROPHOSPHATES WHERE M= NA, K, NH4, RB, CS AND N2H5
    DURAND, J
    GRANIER, W
    COT, L
    AVINENS, C
    COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1973, 277 (01): : 13 - 14
  • [44] A2CuP3S9 (A = K, Rb), Cs2Cu2P2S6, and K3CuP2S7:: New phases from the dissolution of copper in molten polythiophosphate fluxes
    Hanko, JA
    Sayettat, J
    Jobic, S
    Brec, R
    Kanatzidis, MG
    CHEMISTRY OF MATERIALS, 1998, 10 (10) : 3040 - 3049
  • [45] Zeolite-like borosilicates from the Si-rich part of the R2O-B2O3-SiO2 (R = K, Rb, Cs) systems
    Krzhizhanovskaya, Maria G.
    Bubnova, Rimma S.
    Filatov, Stanislav K.
    MINERALS AS ADVANCED MATERIALS I, 2008, : 117 - +
  • [46] Syntheses and crystal structures of a new family of hybrid perovskites: C5H14N2•ABr3•0.5H2O (A = K, Rb, Cs)
    Ferrandin, Sarah
    Slawin, Alexandra M. Z.
    Harrison, William T. A.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 : 1243 - +
  • [47] Phase stability, phonon, electronic, and optical properties of not-yet-synthesized CsScS2, CsYS2, and APmS2 (A= Li, Na, K, Rb, Cs) materials: Insights from first-principles calculations
    Allal, Adel
    Halit, Mohamed
    Saib, Salima
    Luo, Wei
    Ahuja, Rajeev
    MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2022, 150
  • [48] Synthesis and crystal structure of alkali metal oxo nitrido dimetallates(VI), A6[M2N4O3] (A ≡ K, Rb, Cs; M ≡ Mo, W)
    Niewa, R.
    Jacobs, H.
    1600, Elsevier Science S.A., Lausanne, Switzerland (217):
  • [49] SYNTHESIS AND CRYSTAL-STRUCTURE OF ALKALI-METAL OXO NITRIDO DIMETALLATES(VI), A(6)[M(2)N(4)O(3)] (A=K, RB, CS, M=MO, W)
    NIEWA, R
    JACOBS, H
    JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 217 (01) : 38 - 43
  • [50] Iron Vanadates Synthesized from Hydrothermal Brines: Rb2FeV6O16, Cs2FeV6O16, and SrFe3V18O38
    Pellizzeri, Tiffany M. Smith
    McMillen, Colin D.
    Wen, Yimei
    Chumanov, George
    Kolis, Joseph W.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 2019 (42) : 4538 - 4545
12345