A one step processed advanced interwoven architecture of Ni(OH)2 and Cu nanosheets with ultrahigh supercapacitor performance

被引:55
作者
Shi, D. [1 ]
Zhang, L. [1 ]
Yin, X. [1 ]
Huang, T. J. [1 ]
Gong, H. [1 ]
机构
[1] Natl Univ Singapore, Dept Mat Sci & Engn, 7 Engn Dr 1, Singapore 117574, Singapore
关键词
POT HYDROTHERMAL SYNTHESIS; ELECTRODE MATERIALS; NICKEL-HYDROXIDE; OXIDE; GRAPHENE; NANOPARTICLES; NANOWIRES; CARBON; FABRICATION; COMPOSITES;
D O I
10.1039/c6ta03336a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, an interwoven nanoscale structure of Ni(OH)(2) and copper is successfully grown on Ni foam (NF) by using a one-step cheap chemical method. The concurrently formed structure with active Ni(OH)(2) growing together with the conductive Cu network facilitates fast electron transport throughout the electrode. As a result of enhanced conductivity by Cu and ultrathin nanosheet morphology of the active material, the Ni(OH)(2)-Cu hybrid electrode delivers an ultrahigh areal capacitance (8.66 F cm(-2) at 1 mA cm(-2)), superior rate capability (79.1% capacitance retention at 20 mA cm(-2) and 61.8% capacitance retention at 50 mA cm(-2) vs. 1 mA cm(-2)) and outstanding cycling stability (98.5% capacitance retention after being charged/discharged at a series of current densities for 3500 cycles). Furthermore, the full cell, with Ni(OH)(2)-Cu/NF as the positive electrode and reduced graphene oxide (RGO) as the negative electrode, delivers high areal capacitances and superior energy densities especially at high rates. The involved mechanisms are analyzed and discussed.
引用
收藏
页码:12144 / 12151
页数:8
相关论文
共 30 条
[1]   Ternary Ni-Cu-OH and Ni-Co-OH electrodes for electrochemical energy storage [J].
Alhebshi N.A. ;
Alshareef H.N. .
Materials for Renewable and Sustainable Energy, 2015, 4 (04)
[2]   Nickel- Cobalt Layered Double Hydroxide Nanosheets for High- performance Supercapacitor Electrode Materials [J].
Chen, Hao ;
Hu, Linfeng ;
Chen, Min ;
Yan, Yan ;
Wu, Limin .
ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (07) :934-942
[3]   One-pot hydrothermal synthesis of reduced graphene oxide/carbon nanotube/α-Ni(OH)2 composites for high performance electrochemical supercapacitor [J].
Chen, Xi'an ;
Chen, Xiaohua ;
Zhang, Fengqiao ;
Yang, Zhi ;
Huang, Shaming .
JOURNAL OF POWER SOURCES, 2013, 243 :555-561
[4]   Al and Co co-doped α-Ni(OH)2/graphene hybrid materials with high electrochemical performances for supercapacitors [J].
Chen, Xu ;
Long, Conglai ;
Lin, Changpeng ;
Wei, Tong ;
Yan, Jun ;
Jiang, Lili ;
Fan, Zhuangjun .
ELECTROCHIMICA ACTA, 2014, 137 :352-358
[5]   Decoration of Spongelike Ni(OH)2 Nanoparticles onto MWCNTs Using an Easily Manipulated Chemical Protocol for Supercapacitors [J].
Dubal, Deepak P. ;
Gund, Girish S. ;
Lokhande, Chandrakant D. ;
Holze, Rudolf .
ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (07) :2446-2454
[6]   Ternary Hybrids of Amorphous Nickel Hydroxide-Carbon Nanotube-Conducting Polymer for Supercapacitors with High Energy Density, Excellent Rate Capability, and Long Cycle Life [J].
Jiang, Wenchao ;
Yu, Dingshan ;
Zhang, Qiang ;
Goh, Kunli ;
Wei, Li ;
Yong, Yili ;
Jiang, Rongrong ;
Wei, Jun ;
Chen, Yuan .
ADVANCED FUNCTIONAL MATERIALS, 2015, 25 (07) :1063-1073
[7]   Self-Grown Oxy-Hydroxide@ Nanoporous Metal Electrode for High-Performance Supercapacitors [J].
Kang, JianLi ;
Hirata, Akihiko ;
Qiu, H. -J. ;
Chen, LuYang ;
Ge, XingBo ;
Fujita, Takeshi ;
Chen, MingWei .
ADVANCED MATERIALS, 2014, 26 (02) :269-272
[8]   Single-crystalline Ni(OH)2 and NiO nanoplatelet arrays as supercapacitor electrodes [J].
Li, Jiangtian ;
Zhao, Wei ;
Huang, Fuqiang ;
Manivannan, Ayyakkannu ;
Wu, Nianqiang .
NANOSCALE, 2011, 3 (12) :5103-5109
[9]   Ultrafine Ag/MnOx nanowire-constructed hair-like nanoarchitecture: In situ synthesis, formation mechanism and its supercapacitive property [J].
Li, Yonghe ;
Wang, Zhenyu ;
Zhang, Yuefei .
JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 644 :47-53
[10]   Hierarchical mushroom-like CoNi2S4 arrays as a novel electrode material for supercapacitors [J].
Mei, Lin ;
Yang, Ting ;
Xu, Cheng ;
Zhang, Ming ;
Chen, Libao ;
Li, Qiuhong ;
Wang, Taihong .
NANO ENERGY, 2014, 3 :36-45