Oxidation of hydrocarbons by dioxygen reductively activated on platinum and heteropoly compounds

被引：17

作者：

Kuznetsova, NI ^{[1
]}

Kirillova, NV ^{[1
]}

Kuznetsova, LI ^{[1
]}

Likholobov, VA ^{[1
]}

机构：

[1] Boreskov Inst Catalysis, Novosibirsk 630090, Russia

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2003年 / 204卷

关键词：

oxidation; oxygen; hydrogen; cyclohexane; cyclohexene; platinum; heteropoly compound;

D O I：

10.1016/S1381-1169(03)00342-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Based on Pt and heteropoly compounds (HPC), catalysts are applied to liquid-phase oxidation of cyclohexane and cyclohexene with a mixture of O-2 and H-2 gases. Platinum catalyst in the presence of PW11 and PW11Fe HPC represent the most active catalytic systems for alkene oxidation, whereas highest reactivity of cyclohexane was exhibited in the presence of PMo12 HPC. Activity of the catalytic systems and composition of the oxygenated products are controlled by the nature of active intermediates generated under the action of the different HPC. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：591 / 597

页数：7

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