Synthesis and electrochemical behavior of the complex having μ2-nitrosyl moiety, as a two-electron reduction species of a {RuNO}6-type nitrosyl, [{Ru(μ2-NO)}2(2,2-bipy)4]2+

被引：4
作者：
Nagao, H
Nagao, N
Ooyama, D
Sato, Y
Oosawa, T
Kuroda, H
Howell, FS
Mukaida, M
机构：
[1] Sophia Univ, Fac Sci & Engn, Dept Chem, Chiyoda Ku, Tokyo 102, Japan
[2] Stanford Univ, Dept Chem, Stanford, CA 94305 USA
[3] Fukushima Univ, Dept Educ, Fukushima 96012, Japan
来源：
CHEMISTRY LETTERS | 1998年 / 06期
关键词：
D O I：
10.1246/cl.1998.473
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Synthesis of the title complex was accomplished. The structure involving a four-membered cyclic unit with negatively charged NO moieties could be established by C-13 NMR measurements. Its electrochemical behavior was compared with that of [{Ru(mu(2)-NO)}(2)(acac)(4)], which has the same cyclic unit, but with neutral charge on NO(. )moieties. ( )
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页码：473 / 474
页数：2
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