A cyano-bridged coordination nanotube showing field-induced slow magnetic relaxation

被引:35
|
作者
Shao, Dong [1 ]
Shi, Le [1 ]
Shen, Fu-Xing [1 ]
Wang, Xin-Yi [1 ]
机构
[1] Nanjing Univ, Sch Chem & Chem Engn, Collaborat Innovat Ctr Adv Microstruct, State Key Lab Coordinat Chem, Nanjing 210023, Jiangsu, Peoples R China
来源
CRYSTENGCOMM | 2017年 / 19卷 / 38期
关键词
SINGLE-MOLECULE-MAGNET; METAL-ORGANIC FRAMEWORK; ION MAGNETS; COBALT(II) COMPOUNDS; CO(II) COMPLEXES; ANISOTROPY; BEHAVIOR; POLYMER; CO; ARCHITECTURE;
D O I
10.1039/c7ce01436h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Field-induced slow magnetic relaxation was observed in a cyano-bridged coordination nanotube constructed from a pentagonal bi-pyramidal Co-II building block and a hexacyanocobaltate(III) anion, which represents the first example of a coordination nanotube displaying field-induced single-molecule magnet behaviour.
引用
收藏
页码:5707 / 5711
页数:5
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