Conformationally Constrained (Coumarin-Triazolyl-Bipyridyl) Click Fluoroionophore as a Selective Al3+ Sensor

被引：283
作者：
Maity, Debabrata [1 ]
Govindaraju, T. [1 ]
机构：
[1] Jawaharlal Nehru Ctr Adv Sci Res, New Chem Unit, Bioorgan Chem Lab, Bangalore 560064, Karnataka, India
来源：
INORGANIC CHEMISTRY | 2010年 / 49卷 / 16期
关键词：
ALUMINUM TOXICITY; DESIGN; CHEMOSENSORS; COMPLEXES; ZINC(II); IONS;
D O I：
10.1021/ic1009994
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A conformationally constrained (coumarin pyrrolidinyl triazolyl bipyridyl) fluoroionophore conjugate was synthesized through click chemistry. The fluoroionophore serves as a selective chemosensor for Al3+ based on internal charge transfer. The coumarin bipyridyl chemosensor exhibited a high association constant with submicromolar detection for the aluminum ion.
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收藏
页码：7229 / 7231
页数：3
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