A bimetallic complex containing a cyclopentadienyl-annulated imidazol-2-ylidene

被引：58
作者：
Arduengo, AJ
Tapu, D
Marshall, WJ
机构：
[1] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA
[2] DuPont Cent Res, Expt Stn, Wilmington, DE 19880 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 47期
关键词：
D O I：
10.1021/ja055565f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A bimetallic carbene complex architecture that incorporates a cyclopentadienyl-annulated imidazol-2-ylidene moiety is characterized. The ligand architecture enables direct electronic interaction between the π- and σ-bonded metals. A preliminary example of aqueous Suzuki coupling employing a metallocene-fused imidazol-2-ylidene-derived catalyst is described. Copyright © 2005 American Chemical Society.
引用
收藏
页码：16400 / 16401
页数：2
相关论文
共 21 条
[1]   UPON THE STRUCTURE OF ROOM-TEMPERATURE HALOGENOALUMINATE IONIC LIQUIDS [J].
ABDULSADA, AK ;
GREENWAY, AM ;
HITCHCOCK, PB ;
MOHAMMED, TJ ;
SEDDON, KR ;
ZORA, JA .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (24) :1753-1754
[2]   Chelating bis-carbene rhodium(III) complexes in transfer hydrogenation of ketones and imines [J].
Albrecht, M ;
Crabtree, RH ;
Mata, J ;
Peris, E .
CHEMICAL COMMUNICATIONS, 2002, (01) :32-33
[3]   A STABLE CRYSTALLINE CARBENE [J].
ARDUENGO, AJ ;
HARLOW, RL ;
KLINE, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) :361-363
[4]   A zwitterionic cyclopentadienyl annulated imidazolium salt [J].
Arduengo, AJ ;
Bannenberg, TP ;
Tapu, D ;
Marshall, WJ .
TETRAHEDRON LETTERS, 2005, 46 (40) :6847-6850
[5]   Heteroferrocene:: The synthesis of bis[(3a,4,5,6,6a-η)-1,3,4,5,6-pentamethylcyclopenta[d]imidazo-2-thionoyl]iron(II) [J].
Arduengo, AJ ;
Bannenberg, TP ;
Tapu, D ;
Marshall, WJ .
CHEMISTRY LETTERS, 2005, 34 (07) :1010-1011
[6]   Chelating alkoxy-N-heterocyclic carbene complexes of silver and copper [J].
Arnold, PL ;
Scarisbrick, AC ;
Blake, AJ ;
Wilson, C .
CHEMICAL COMMUNICATIONS, 2001, (22) :2340-2341
[7]   N,N′-diferrocenyl-N-heterocyclic carbenes and their derivatives [J].
Bildstein, B ;
Malaun, M ;
Kopacka, H ;
Wurst, K ;
Mitterböck, M ;
Ongania, KH ;
Opromolla, G ;
Zanello, P .
ORGANOMETALLICS, 1999, 18 (21) :4325-4336
[8]   Imidazoline-2-ylidene metal complexes with pendant ferrocenyl substituents [J].
Bildstein, B ;
Malaun, M ;
Kopacka, H ;
Ongania, KH ;
Wurst, K .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 552 (1-2) :45-61
[9]   HIGHER OXIDATION-STATE CHEMISTRY OF OSMOCENE - DIMERIC NATURE OF THE OSMOCENIUM ION [J].
DROEGE, MW ;
HARMAN, WD ;
TAUBE, H .
INORGANIC CHEMISTRY, 1987, 26 (08) :1309-1315
[10]   MOLECULAR ENGINEERING OF SOLID-STATE MATERIALS - ORGANOMETALLIC BUILDING-BLOCKS [J].
FAGAN, PJ ;
WARD, MD ;
CALABRESE, JC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (05) :1698-1719
123