Molecular tilting and columnar stacking of Fe phthalocyanine thin films on Au(111)

被引：14

作者：

Bartolome, F. ^{[1
]}

Bunau, O. ^{[1
]}

Garcia, L. M. ^{[1
]}

Natoli, C. R. ^{[2
]}

Piantek, M. ^{[1
,3
]}

Pascual, J. I. ^{[3
,4
,5
]}

Schuller, I. K. ^{[6
,7
]}

Gredig, T. ^{[8
]}

Wilhelm, F. ^{[9
]}

Rogalev, A. ^{[9
]}

Bartolome, J. ^{[1
]}

机构：

[1] Univ Zaragoza, CSIC, Dept Fis Mat Condensada, ICMA, E-50009 Zaragoza, Spain

[2] Ist Nazl Fis Nucl, Lab Nazl Frascati, I-00044 Frascati, Italy

[3] Univ Zaraqoza, Inst Nanociencia Aragon, Lab Microscopias Avanzadas, E-50018 Zaragoza, Spain

[4] Basque Fdn Sci, CIC NanoGUNE, San Sebastian 20018, Spain

[5] Basque Fdn Sci, Ikerbasque, San Sebastian 20018, Spain

[6] Univ Calif San Diego, Dept Phys, La Jolla, CA 92093 USA

[7] Univ Calif San Diego, Ctr Adv Nanotechnol, La Jolla, CA 92093 USA

[8] Calif State Univ Long Beach, Dept Phys & Astron, Long Beach, CA 90840 USA

[9] ESRF, F-38043 Grenoble 9, France

来源：

JOURNAL OF APPLIED PHYSICS | 2015年 / 117卷 / 17期

基金：

美国国家科学基金会; 奥地利科学基金会;

关键词：

Molecules - Scanning tunneling microscopy - Substrates - X ray absorption - Absorption spectroscopy;

D O I：

10.1063/1.4916302

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Scanning tunneling microscopy and x-ray absorption spectroscopic results at the Fe K edge of Fe phthalocyanine (FePc) thin films grown on Au substrates, together with theoretical calculations, allow us to refine the structure of the film. In particular, we show that the columnar stacking of the FePc molecules is different from that found in bulk alpha and beta phases. Moreover, the molecules do not lay parallel to the surface of the substrate. These structural findings are relevant to understand magnetism of FePc films. (C) 2015 AIP Publishing LLC.

引用

页数：4

共 18 条

[1] Molecular layers of ZnPc and FePc on Au(111) surface: Charge transfer and chemical interaction [J].

Ahmadi, Sareh ;

Shariati, M. Nina ;

Yu, Shun ;

Gothelid, Mats .

JOURNAL OF CHEMICAL PHYSICS, 2012, 137 (08)

[2] Highly unquenched orbital moment in textured Fe-phthalocyanine thin films [J].

Bartolome, J. ;

Bartolome, F. ;

Garcia, L. M. ;

Filoti, G. ;

Gredig, T. ;

Colesniuc, C. N. ;

Schuller, I. K. ;

Cezar, J. C. .

PHYSICAL REVIEW B, 2010, 81 (19)

[3] Self-consistent aspects of x-ray absorption calculations [J].

Bunau, O. ;

Joly, Y. .

JOURNAL OF PHYSICS-CONDENSED MATTER, 2009, 21 (34)

[4] Probing Superexchange Interaction in Molecular Magnets by Spin-Flip Spectroscopy and Microscopy [J].

Chen, Xi ;

Fu, Ying-Shuang ;

Ji, Shuai-Hua ;

Zhang, Tong ;

Cheng, Peng ;

Ma, Xu-Cun ;

Zou, Xiao-Long ;

Duan, Wen-Hui ;

Jia, Jin-Feng ;

Xue, Qi-Kun .

PHYSICAL REVIEW LETTERS, 2008, 101 (19)

[5] Epitaxial growth of iron phthalocyanine at the initial stage on Au(111) surface [J].

Cheng, Z. H. ;

Gao, L. ;

Deng, Z. T. ;

Liu, Q. ;

Jiang, N. ;

Lin, X. ;

He, X. B. ;

Du, S. X. ;

Gao, H. -J. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (06) :2656-2660

[6]

Ercolani C., 1967, Inorg. Chim. Acta, V1, P415

[7]

Evangelisti M., 2004, ENCY SUPRAMOLECULAR, P1069

[8] Mossbauer study of the hyperfine interactions and spin dynamics in α-iron(II) phthalocyanine [J].

Filoti, G. ;

Kuz'min, M. D. ;

Bartolome, J. .

PHYSICAL REVIEW B, 2006, 74 (13)

[9] Substrate-controlled ferromagnetism in iron phthalocyanine films due to one-dimensional iron chains [J].

Gredig, Thomas ;

Colesniuc, Corneliu N. ;

Crooker, Scott A. ;

Schuller, Ivan K. .

PHYSICAL REVIEW B, 2012, 86 (01)

[10] Control of magnetic properties in metallo-organic thin films [J].

Gredig, Thomas ;

Gentry, K. Paul ;

Colesniuc, Corneliu N. ;

Schuller, Ivan K. .

JOURNAL OF MATERIALS SCIENCE, 2010, 45 (18) :5032-5035

← 1 2 →