N2S2-donor macrocycles with some transition metal ions:: Synthesis and characterization

被引：11
|
作者：
Nasman, Omar S. M. [1 ]
机构：
[1] Al Azhar Univ, Dept Chem, Gaza, Israel
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2008年 / 183卷 / 07期
关键词：
15-membered diaza-dithiamacrocyclic complexes; template synthesis; Co(II); Cu(II); Fe(II); Ni(II); Zn(II);
D O I：
10.1080/10426500701690939
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel series of 15-membered diaza-dithiamacrocyclic complexes (ML1Cl2) and (ML2Cl2) (M=Fe,Co, Ni, Cu, and Zn) have been prepared by the template condensation reaction of o-thiosalicylic acid with aliphatic or aromatic diamines and diethyl malonate in the presence of transition metal ions in alcoholic medium and have been characterized through IR, (HNMR)-H-1 and electronic spectral studies, conductivity and magnetic susceptibility measurements. An octahedral geometry has been suggested for all complexes.
引用
收藏
页码：1541 / 1551
页数：11
相关论文
共 50 条
  • [1] Synthesis and characterization of metal-free phthalocyanine containing 16-membered N2S2-donor macrocycles linked to a 2-pyridinyl methyl moiety
    Kabay, Nilgun
    Gok, Yasar
    TETRAHEDRON LETTERS, 2013, 54 (31) : 4086 - 4090
  • [2] Macrocyclic ligand design:: The interaction of selected transition and post-transition metal ions with a 14-membered N2S2-donor macrocycle
    Chartres, Jy D.
    Davies, Murray S.
    Lindoy, Leonard F.
    Meehan, George V.
    Wei, Gang
    INORGANIC CHEMISTRY COMMUNICATIONS, 2006, 9 (07) : 751 - 754
  • [3] Synthesis and characterization of novel macrocycles and their complexes with transition metal ions
    Tabassum, S
    Rafiqi, SH
    Arjmand, F
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 2002, 32 (05): : 949 - 966
  • [4] INTERACTION OF TRANSITION-METAL AND POST-TRANSITION-METAL IONS WITH O2N2-DONOR MACROCYCLES INCORPORATING PENDANT PYRIDYLMETHYL GROUPS
    ADAM, KR
    LINDOY, LF
    SKELTON, BW
    SMITH, SV
    WHITE, AH
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (23): : 3361 - 3367
  • [5] Metal ion recognition.: Selective interaction of silver(I) with tri-linked N2S2-donor macrocycles and their single-ring analogues
    Chartres, JD
    Groth, AM
    Lindoy, LF
    Meehan, GV
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (03): : 371 - 376
  • [6] Synthesis and characterization of the copper(II) complexes of new N2S2-donor macrocyclic ligands: synthesis and in vivo evaluation of the 64Cu complexes
    Papini, Grazia
    Alidori, Simone
    Lewis, Jason S.
    Reichert, David E.
    Pellei, Maura
    Lobbia, Giancarlo Gioia
    Biddlecombe, Grainne B.
    Anderson, Carolyn J.
    Santini, Carlo
    DALTON TRANSACTIONS, 2009, (01) : 177 - 184
  • [7] Copper(II) template synthesis of a new N2S2-donor macrocycle incorporating a pendent pyridyl substituent
    Mora, Cindy
    Lee, Young Hoon
    Clegg, Jack K.
    Lindoy, Leonard F.
    Lee, Hong In
    Lim, Woo Taik
    Kim, Yang
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2011, 71 (3-4) : 389 - 394
  • [8] Synthesis and metal-ion binding properties of new N2S4- and N2S5-donor macrocycles
    Alp, Hakan
    Biyikliojlu, Zekeriya
    Dilber, Gulsev
    Ocak, Ummuhan
    Marap, Aysel
    Kantekin, Halit
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2007, 58 (3-4) : 283 - 288
  • [9] Synthesis and metal-ion binding properties of new N2S4- and N2S5-donor macrocycles
    Hakan Alp
    Zekeriya Biyiklioğlu
    Gülsev Dilber
    ÜmmÜhan Ocak
    Aysel Marap
    Halit Kantekin
    Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2007, 58 : 283 - 288
  • [10] Transition metal complexes of 13- and 14-membered N2O2 macrocycles: synthesis and characterization
    Omar S. M. Nasman
    Transition Metal Chemistry, 2008, 33 : 285 - 288
12345