Structural and spectral studies of a new copper(II) complex with a tridentate thiosemicarbazone ligand

被引：17
|
作者：
Sen, Soma [1 ]
Shit, Shyamapada [1 ]
Mitra, Samiran [1 ]
Batten, Stuart R. [2 ]
机构：
[1] Univ Jadavpur, Dept Chem, Kolkata 700032, W Bengal, India
[2] Monash Univ, Dept Chem, Clayton, Vic, Australia
来源：
STRUCTURAL CHEMISTRY | 2008年 / 19卷 / 01期
关键词：
Cu(II); thiosemicarbazone ligand; X-ray structure; spectroscopic; electrochemical; thermal analysis;
D O I：
10.1007/s11224-007-9263-x
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of copper(II) chloride dihydrate with 2-hydroxy-3-methoxybenzaldehydethiosemicarbazone (HL) ligand in a 1: 1 ratio forms the complex [Cu(L)(Cl)] center dot H2O. The complex is characterized by spectroscopic, electrochemical, and thermal analysis. X-ray crystallographic analysis reveals that the central copper atom displays the distorted square planar geometry. The water molecule present in the lattice participates in a strong hydrogen bonding network, which leads to a 2D supramolecular arrangement.
引用
收藏
页码：137 / 142
页数：6
相关论文
共 50 条
  • [1] Structural and spectral studies of a new copper(II) complex with a tridentate thiosemicarbazone ligand
    Soma Sen
    Shyamapada Shit
    Samiran Mitra
    Stuart R. Batten
    Structural Chemistry, 2008, 19 : 137 - 142
  • [2] A copper(II) complex of a new chiral tridentate imidazoline ligand
    Bohnen, FM
    Goddard, R
    Minidis, ABE
    Alexakis, A
    Pfaltz, A
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 1236 - 1238
  • [3] Synthesis and Spectral Studies of Some Lanthanide Complexes with Tridentate Thiosemicarbazone Ligand
    Kumar, Dubey Raj
    Ayesha, Mariya
    RESEARCH JOURNAL OF CHEMISTRY AND ENVIRONMENT, 2011, 15 (01): : 5 - 11
  • [4] Synthesis and spectral studies on copper(II) and cobalt(II) complexes of macrocyclic ligand containing thiosemicarbazone moiety
    Chandra, S
    Sangeetika
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2002, 41 (08): : 1629 - 1633
  • [5] Spectral, magnetic, thermal and electrochemical studies on new copper(II) thiosemicarbazone complexes
    Al-Hazmi, GAA
    El-Shahawi, MS
    Gabr, IM
    El-Asmy, AA
    JOURNAL OF COORDINATION CHEMISTRY, 2005, 58 (08) : 713 - 733
  • [6] Structural and spectral studies of nickel(II), copper(II) and cadmium(II) complexes of 3-furaldehyde thiosemicarbazone
    El Mostapha, J
    Allain, M
    Khan, MA
    Bouet, GM
    POLYHEDRON, 2005, 24 (02) : 327 - 332
  • [7] THIOSEMICARBAZONE COMPLEXES OF COPPER(II) - STRUCTURAL AND BIOLOGICAL STUDIES
    WEST, DX
    LIBERTA, AE
    PADHYE, SB
    CHIKATE, RC
    SONAWANE, PB
    KUMBHAR, AS
    YERANDE, RG
    COORDINATION CHEMISTRY REVIEWS, 1993, 123 (1-2) : 49 - 71
  • [8] A new mononuclear copper (II) complex with an O,N,O'-tridentate Schiff base ligand: Synthesis, structural, Hirshfeld surface, electrochemical and theoretical studies
    Hafidi, Radia
    Messai, Amel
    Chebbah, Mahmoud
    Kadri, Rayene
    Labidi, Nouar Sofiane
    Kadri, Mekki
    INORGANIC CHEMISTRY COMMUNICATIONS, 2024, 159
  • [9] Structural Investigation of a Novel Copper(II) Complex with Pyridoxal Thiosemicarbazone
    Chagas, M. A. S.
    Gatto, C. C.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2018, 74 : A12 - A12
  • [10] Synthesis and characterization of a novel copper (II) complex coordinated to a thiosemicarbazone ligand
    Rowand, Margaret
    Weigand, Willis
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
12345