Construction of SnO2/g-C3N4 an effective nanocomposite for photocatalytic degradation of amoxicillin and pharmaceutical effluent

被引:80
作者
Nivetha, Michael Raj Sherlin [1 ]
Kumar, Jothi Vinoth [1 ]
Ajarem, Jamaan S. [2 ]
Allam, Ahmed A. [3 ]
Manikandan, Velu [4 ]
Arulmozhi, Rajaram [1 ]
Abirami, Natarajan [1 ]
机构
[1] SRM Inst Sci & Technol, Coll Engn & Technol, Dept Chem, Kattankulathur 603203, Tamil Nadu, India
[2] King Saud Univ, Coll Sci, Zool Dept, Riyadh, Saudi Arabia
[3] Beni Suef Univ, Fac Sci, Zool Dept, Bani Suwayf, Egypt
[4] Gachon Univ, Dept BioNano Technol, 1342 Seongnam Daero, Seongnam Si 13120, Gyeonggi Do, South Korea
关键词
Green synthesis; SnO2/g-C3N4; nanocomposite; Amoxicillin; Pharmaceutical effluent; Photocatalytic activity; SNO2; NANOPARTICLES; TERNARY NANOCOMPOSITE; OXIDE NANOPARTICLES; G-C3N4; NANOSHEETS; CHARGE-TRANSFER; GREEN SYNTHESIS; BAND-GAP; REDUCTION; PERFORMANCE; WATER;
D O I
10.1016/j.envres.2022.112809
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The current study mainly focused on the fabrication of 2D graphitic carbon nitride-supported tin oxide nanoparticles (SnO2/g-C3N4) for the effective degradation of Amoxicillin (AMX). Tin oxide (SnO2) NPs were prepared by green and easy modification technique, and then it is decorated over g-C3N4 nanosheets. The structural morphology and surface composition of the synthesized SnO2/g-C3N4 nanocomposite were fully analysed by UV-Vis, XRD, XPS, and HR-SEM with EDAX, FT-IR, and BET analysis. The (HR-TEM) microscopy, the size of SnO2 NPs which as a diameter is about 6.2 nm. The Raman analysis revealed that the SnO2/g-C3N4 composite had a moderate graphitic structure, with a measured I-D/I-g value of 0.79. The degradation efficiency of antibiotic pollutant AMX and pharma effluent treatment was monitored by UV spectroscopy. The optical band gap of SnO2 (2.9 eV) and g-C3N4 (2.8 eV) photocatalyst was measured by Tauc plots. To investigate the mechanism through the photodegradation efficiency of the catalyst was analysed by using different Scavenger EDTA-2Na holes (h(+)) has a greater contribution towards the degradation process. Under visible irradiation, SnO2/g-C3N4 nanocomposite has exhibited an excellent degradation performance of 92.1% against AMX and 90.8% for pharmaceutical effluent in 80 min.
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页数:12
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