Construction of SnO2/g-C3N4 an effective nanocomposite for photocatalytic degradation of amoxicillin and pharmaceutical effluent

被引:80
作者
Nivetha, Michael Raj Sherlin [1 ]
Kumar, Jothi Vinoth [1 ]
Ajarem, Jamaan S. [2 ]
Allam, Ahmed A. [3 ]
Manikandan, Velu [4 ]
Arulmozhi, Rajaram [1 ]
Abirami, Natarajan [1 ]
机构
[1] SRM Inst Sci & Technol, Coll Engn & Technol, Dept Chem, Kattankulathur 603203, Tamil Nadu, India
[2] King Saud Univ, Coll Sci, Zool Dept, Riyadh, Saudi Arabia
[3] Beni Suef Univ, Fac Sci, Zool Dept, Bani Suwayf, Egypt
[4] Gachon Univ, Dept BioNano Technol, 1342 Seongnam Daero, Seongnam Si 13120, Gyeonggi Do, South Korea
关键词
Green synthesis; SnO2/g-C3N4; nanocomposite; Amoxicillin; Pharmaceutical effluent; Photocatalytic activity; SNO2; NANOPARTICLES; TERNARY NANOCOMPOSITE; OXIDE NANOPARTICLES; G-C3N4; NANOSHEETS; CHARGE-TRANSFER; GREEN SYNTHESIS; BAND-GAP; REDUCTION; PERFORMANCE; WATER;
D O I
10.1016/j.envres.2022.112809
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The current study mainly focused on the fabrication of 2D graphitic carbon nitride-supported tin oxide nanoparticles (SnO2/g-C3N4) for the effective degradation of Amoxicillin (AMX). Tin oxide (SnO2) NPs were prepared by green and easy modification technique, and then it is decorated over g-C3N4 nanosheets. The structural morphology and surface composition of the synthesized SnO2/g-C3N4 nanocomposite were fully analysed by UV-Vis, XRD, XPS, and HR-SEM with EDAX, FT-IR, and BET analysis. The (HR-TEM) microscopy, the size of SnO2 NPs which as a diameter is about 6.2 nm. The Raman analysis revealed that the SnO2/g-C3N4 composite had a moderate graphitic structure, with a measured I-D/I-g value of 0.79. The degradation efficiency of antibiotic pollutant AMX and pharma effluent treatment was monitored by UV spectroscopy. The optical band gap of SnO2 (2.9 eV) and g-C3N4 (2.8 eV) photocatalyst was measured by Tauc plots. To investigate the mechanism through the photodegradation efficiency of the catalyst was analysed by using different Scavenger EDTA-2Na holes (h(+)) has a greater contribution towards the degradation process. Under visible irradiation, SnO2/g-C3N4 nanocomposite has exhibited an excellent degradation performance of 92.1% against AMX and 90.8% for pharmaceutical effluent in 80 min.
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页数:12
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共 67 条
[1]   A critical review on the formation, fate and degradation of the persistent organic pollutant hexachlorocyclohexane in water systems and waste streams [J].
Adithya, Srikanth ;
Jayaraman, Ramesh Sai ;
Krishnan, Abhishek ;
Malolan, Rajagopal ;
Gopinath, Kannappan Panchamoorthy ;
Arun, Jayaseelan ;
Kim, Woong ;
Govarthanan, Muthusamy .
CHEMOSPHERE, 2021, 271
[2]   Electrochemical detection of ammonia solution using tin oxide nanoparticles synthesized via sol-gel route [J].
Arya, Sandeep ;
Riyas, Mohammad ;
Sharma, Asha ;
Singh, Bikram ;
Prerna ;
Bandhoria, Pankaj ;
Khan, Saleem ;
Bharti, Vishal .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2018, 124 (08)
[3]   Photocatalytic degradation of amoxicillin from aqueous solutions by titanium dioxide nanoparticles loaded on graphene oxide [J].
Balarak, Davoud ;
Mengelizadeh, Nezamaddin ;
Rajiv, Periakaruppan ;
Chandrika, Kethineni .
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2021, 28 (36) :49743-49754
[4]   Sargassum myriocystum-mediated TiO2-nanoparticles and their antimicrobial, larvicidal activities and enhanced photocatalytic degradation of various dyes [J].
Balaraman, Perumal ;
Balasubramanian, Balamuralikrishnan ;
Liu, Wen-Chao ;
Kaliannan, Durairaj ;
Durai, Mahendran ;
Kamyab, Hesam ;
Alwetaishi, Mamdooh ;
Maluventhen, Viji ;
Ashokkumar, Veeramuthu ;
Chelliapan, Shreeshivadasan ;
Maruthupandian, Arumugam .
ENVIRONMENTAL RESEARCH, 2022, 204
[5]   AgCl/Ag/g-C3N4 Hybrid Composites: Preparation, Visible Light-Driven Photocatalytic Activity and Mechanism [J].
Bao, Yongchao ;
Chen, Kezheng .
NANO-MICRO LETTERS, 2016, 8 (02) :182-192
[6]   A novel approach for the synthesis of SnO2 nanoparticles and its application as a catalyst in the reduction and photodegradation of organic compounds [J].
Bhattacharjee, Archita ;
Ahmaruzzaman, M. ;
Sinha, Tanur .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2015, 136 :751-760
[7]   Synthesis of g-C3N4 nanosheet modified SnO2 composites with improved performance for ethanol gas sensing [J].
Cao, Jianliang ;
Qin, Cong ;
Wang, Yan ;
Zhang, Huoli ;
Zhang, Bo ;
Gong, Yuxiao ;
Wang, Xiaodong ;
Sun, Guang ;
Bala, Hari ;
Zhang, Zhanying .
RSC ADVANCES, 2017, 7 (41) :25504-25511
[8]   Noble metal-free g-C3N4/TiO2/CNT ternary nanocomposite with enhanced photocatalytic performance under visible-light irradiation via multi-step charge transfer process [J].
Chaudhary, Deepti ;
Vankar, V. D. ;
Khare, Neeraj .
SOLAR ENERGY, 2017, 158 :132-139
[9]   A magnetic CoFe2O4-CNS nanocomposite as an efficient, recyclable catalyst for peroxymonosulfate activation and pollutant degradation [J].
Chen, Chang-Bin ;
Zhang, Feng ;
Li, Chen-Xuan ;
Lu, Jia-Yuan ;
Cui, Shuo ;
Liu, Hou-Qi ;
Li, Wen-Wei .
RSC ADVANCES, 2017, 7 (87) :55020-55025
[10]   A facile one-pot reduction method for the preparation of a SnO/SnO2/GNS composite for high performance lithium ion batteries [J].
Chen, Xiao-Ting ;
Wang, Kai-Xue ;
Zhai, Yu-Bo ;
Zhang, Hao-Jie ;
Wu, Xue-Yan ;
Wei, Xiao ;
Chen, Jie-Sheng .
DALTON TRANSACTIONS, 2014, 43 (08) :3137-3143