Electrical properties and leakage current behavior of un-doped and Ti-doped lea zirconate thin films synthesized by sol-gel method

被引：15

作者：

Alkoy, Ebru Mensur ^{[1
,2
]}

Shiosaki, Tadashi ^{[2
]}

机构：

[1] Kocaeli Univ, Grad Sch Nat & Appl Sci, Izmit, Kocaeli, Turkey

[2] Nara Inst Sci & Technol, Grad Sch Mat Sci, Nara 6300101, Japan

来源：

THIN SOLID FILMS | 2008年 / 516卷 / 12期

关键词：

lead zirconate; antiferroelectrics; thin film; doping; leakage current;

D O I：

10.1016/j.tsf.2007.08.046

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Un-doped and Ti-doped (5, 10 and 15 mol%) antiferroelectric and ferroelectric lead zirconate-PbZrO3 (PZ) thin films were prepared by sol-gel spin coating method. All PZ films crystallized in the perovskite phase with full [111] pseudocubic orientation with a uniform microstructure. The paraelectric-ferroelectric phase transition temperature was found to shift to lower values and the electrical properties were found to degrade as a result of decreasing film thickness. The leakage current of the un-doped PZ films were dominated by the space-charge-fimited current, whereas Poole-Frenkel conduction mechanism was found to be dominant at the Ti-doped films at high electric fields. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：4002 / 4010

页数：9

共 35 条

[21] Irreversibility of the antiferroelectric to ferroelectric phase transition in (Pb0.90Ba0.10)ZrO3 ceramics
Pokharel, BP
Pandey, D
[J]. JOURNAL OF APPLIED PHYSICS, 1999, 86 (06) : 3327 - 3332
[22] Texture control and ferroelectric properties of Pb(Nb,Zr,Sn,Ti)O3 thin films prepared by chemical solution method
Qu, WG
Tan, XL
[J]. THIN SOLID FILMS, 2006, 496 (02) : 383 - 388
[23] Scott J. F., 2000, FERROELECTRIC MEMORI, P91
[24] Preparation of antiferroelectric PbZrxTi1-xO3 thin films on LaSrMnO3-coated steel substrates
Seveno, R
Gundel, HW
Seifert, S
[J]. APPLIED PHYSICS LETTERS, 2001, 79 (25) : 4204 - 4206
[25] CRYSTAL STRUCTURE OF PB(ZR-TI)O3
SHIRANE, G
SUZUKI, K
[J]. JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1952, 7 (03) : 333 - 333
[26] PHASE TRANSITIONS IN SOLID SOLUTIONS OF PBZRO3 AND PBTIO3 .1. SMALL CONCENTRATIONS OF PBTIO3
SHIRANE, G
TAKEDA, A
[J]. JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1952, 7 (01) : 5 - 11
[27] PHASE TRANSITIONS IN SOLID SOLUTIONS OF PBZRO3 AND PBTIO3 .2. X-RAY STUDY
SHIRANE, G
SUZUKI, K
TAKEDA, A
[J]. JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1952, 7 (01) : 12 - 18
[28] Microstructure and optical properties of amorphous and crystalline PbZrO3 thin films grown on Si(100) substrates by a sol-gel process
Tang, XG
Zeng, HR
Ding, AL
Qiu, PS
Luo, WG
Li, HQ
Mo, D
[J]. SOLID STATE COMMUNICATIONS, 2000, 116 (09) : 507 - 511
[29] Effect of Zr/Ti ratio on microstructure and electrical properties of lead zirconate titanate thin films derived by pulsed laser deposition
Wang, ZJ
Aoki, Y
Kokawa, H
Ichiki, M
Maeda, R
[J]. JOURNAL OF ELECTROCERAMICS, 2004, 13 (1-3) : 41 - 45
[30] Dependence of electrical properties on film thickness in lanthanum-doped lead zirconate titanate stannate antiferroelectric thin films
Xu, BM
Ye, YH
Wang, QM
Cross, LE
[J]. JOURNAL OF APPLIED PHYSICS, 1999, 85 (07) : 3753 - 3758

← 1 2 3 4 →