Redox synthesis and high catalytic efficiency of transition-metal nanoparticle-graphene oxide nanocomposites

被引：27

作者：

Wang, Changlong ^{[1
,2
]}

Ciganda, Roberto ^{[1
]}

Yate, Luis ^{[3
]}

Tuninetti, Jimena ^{[3
,4
]}

Shalabaeva, Victoria ^{[2
]}

Salmon, Lionel ^{[2
]}

Moya, Sergio ^{[3
]}

Ruiz, Jaime ^{[1
]}

Astruc, Didier ^{[1
]}

机构：

[1] Univ Bordeaux, CNRS 5255, UMR, ISM, F-33405 Talence, France

[2] CNRS, UPR 8241, Lab Chim Coordinat, F-31077 Toulouse, France

[3] CCIC BiomaGUNE, Unidad Biosuperficies, Paseo Miramon 182,Edif C, Donostia San Sebastian 20009, Spain

[4] Univ Nacl La Plata, CONICET, Inst Invest Fisicoquim Teor & Aplicadas INIFTA, Diagonal 113 & 64, RA-1900 La Plata, Argentina

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2017年 / 5卷 / 41期

关键词：

CHEMICAL HYDROGEN STORAGE; SPHERICAL POLYELECTROLYTE BRUSHES; BOND-DISSOCIATION ENERGIES; AQUEOUS AMMONIA-BORANE; HYDROLYTIC DEHYDROGENATION; HETEROGENEOUS CATALYSIS; RHODIUM NANOPARTICLES; ALLOY NANOPARTICLES; GOLD NANOPARTICLES; COUPLING REACTIONS;

D O I：

10.1039/c7ta06182j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Although nanocatalysis is a promising area, increased efficiency and greenness are actively sought. Here we report the principle of the syntheses of graphene oxide (GO)-supported metal nanocatalysts (MNPs) for a variety of transition metals including both noble metals and biometal using either exergonic or endergonic redox reactions between GO and the transition metal salts. These new nanocatalysts are highly efficient in water at ambient temperature for 4-nitrophenol reduction (the test reaction), Sonogashira coupling, azide-alkyne 1,3-cycloaddition (click reaction) and dihydrogen production upon hydrolysis of ammonia-borane and recyclable.

引用

页码：21947 / 21954

页数：8

共 87 条

[51] Metal Nanocrystals Embedded in Single Nanocrystals of MOFs Give Unusual Selectivity as Heterogeneous Catalysts [J].

Na, Kyungsu ;

Choi, Kyung Min ;

Yaghi, Omar M. ;

Somorjai, Gabor A. .

NANO LETTERS, 2014, 14 (10) :5979-5983

[52] Metal nanoparticles supported on two-dimensional graphenes as heterogeneous catalysts [J].

Navalon, Sergio ;

Dhakshinamoorthy, Amarajothi ;

Alvaro, Mercedes ;

Garcia, Hermenegildo .

COORDINATION CHEMISTRY REVIEWS, 2016, 312 :99-148

[53] Carbocatalysis by Graphene-Based Materials [J].

Navalon, Sergio ;

Dhakshinamoorthy, Amarajothi ;

Alvaro, Mercedes ;

Garcia, Hermenegildo .

CHEMICAL REVIEWS, 2014, 114 (12) :6179-6212

[54] Removal and Utilization of Capping Agents in Nanocatalysis [J].

Niu, Zhiqiang ;

Li, Yadong .

CHEMISTRY OF MATERIALS, 2014, 26 (01) :72-83

[55] Rhodium(0) nanoparticles supported on nanosilica: Highly active and long lived catalyst in hydrogen generation from the methanolysis of ammonia borane [J].

Ozhava, Derya ;

Ozkar, Saim .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2016, 181 :716-726

[56] A Facile and Novel Synthesis of Ag-Graphene-Based Nanocomposites [J].

Pasricha, Renu ;

Gupta, Shweta ;

Srivastava, Avanish Kumar .

SMALL, 2009, 5 (20) :2253-2259

[57] High-accuracy coupled-cluster computations of bond dissociation energies in SH, H2S, and H2O [J].

Peebles, LR ;

Marshall, P .

JOURNAL OF CHEMICAL PHYSICS, 2002, 117 (07) :3132-3138

[58] Catalysis by Design: Well-Defined Single-Site Heterogeneous Catalysts [J].

Pelletier, Jeremie D. A. ;

Basset, Jean-Marie .

ACCOUNTS OF CHEMICAL RESEARCH, 2016, 49 (04) :664-677

[59] On the nature of the active species in palladium catalyzed Mizoroki-Heck and Suzuki-Miyaura couplings - Homogeneous or heterogeneous catalysis, a critical review [J].

Phan, NTS ;

Van Der Sluys, M ;

Jones, CW .

ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (06) :609-679

[60] Silver nanoparticle catalyzed reduction of aromatic nitro compounds [J].

Pradhan, N ;

Pal, A ;

Pal, T .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2002, 196 (2-3) :247-257

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