Electrocatalysis of 5-hydroxymethylfurfural at cobalt based spinel catalysts with filamentous nanoarchitecture in alkaline media

被引：185

作者：

Kang, Myung Jong ^{[1
]}

Park, Heesun ^{[2
]}

Jegal, Jonggeon ^{[2
]}

Hwang, Sung Yeon ^{[2
,3
]}

Kang, Young Soo ^{[1
]}

Cha, Hyun Gil ^{[2
]}

机构：

[1] Sogang Univ, Dept Chem, Korea Ctr Artificial Photosynth, Seoul 04107, South Korea

[2] Korea Res Inst Chem Technol, Res Ctr Biobased Chem, Ulsan 44412, South Korea

[3] Univ Sci & Technol, Adv Mat & Chem Engn, Daejeon 34113, South Korea

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 2019年 / 242卷

关键词：

Spinel structure; 5-Hydroxylmethylfurfural; Electrocatalysis; 2,5-Furandicarboxylic acid; AEROBIC OXIDATION; 2,5-FURANDICARBOXYLIC ACID; SELECTIVE OXIDATION; BIOMASS CONVERSION; SURFACE; OXIDES; OXYGEN; WATER;

D O I：

10.1016/j.apcatb.2018.09.087

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This study reports the activity of cobalt based metal oxide electrode with spinel structure for 5-hydroxymethylfurfural (HMF) oxidation. For that purpose, the Co3O4 and NiCo2O4 electrode with filamentous nanoarchitecture were grown on Ni foam by a hydrothermal method and then characterized by means of SEM, TEM, and XPS analyses. During electrochemical oxidation of HMF, the role of Co3+ in Co3O4 and NiCo2O4 spinel structure was investigated by}CANES. The filamentous nanoarchitecture of NiCo2O4 showed 99.6% 5-hydroxymethylfurfural (HMF) conversion efficiency with 90.8% selectivity on 2,5-furandicarboxylic acid (FDCA). The catalyst was successfully recycled up to three times, retaining over 80% of FDCA conversion efficiency. These results demonstrated the potential interest of NiCo2O4 anodic catalyst, prepared via hydrothermal method, for production of high-valued chemical from biomass-derived compounds via electrochemical techniques.

引用

页码：85 / 91

页数：7

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