Stannasiloxanes: from rings to polymers

被引：97
作者：
Beckmann, J [1 ]
Jurkschat, K [1 ]
机构：
[1] Univ Dortmund, Lehrstuhl Anorgan Chem 2, D-44221 Dortmund, Germany
来源：
COORDINATION CHEMISTRY REVIEWS | 2001年 / 215卷
关键词：
silicon; tin; siloxane; polymerization;
D O I：
10.1016/S0010-8545(01)00319-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A review is given with 140 references on the recent progress in the chemistry of cyclo-stannasiloxanes of different ring size, such as cyclo-R2Sn(OSiR2')(2)O, cyclo-R2Sn(OSiPh2O)(2)SnR2, cycle -R2Sn(OSiPh2O)(2)SiPh2, cycle -R2Sn(OSiPh2)(2)SiPh2 and cyclo-R2Sn(OSiPh2)(2) (R = alkyl, aryl, intramolecularly coordinating built-in ligand, transition metal fragment; R ' =Me, i-Pr, Ph); and their potential in ring-opening polymerization reactions is critically evaluated and compared with that of related cyclo-borasiloxanes, cyclo-germasiloxanes, and cyclo-siloxanes. (C) 2001 Elsevier Science B.V. All rights reserved.
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收藏
页码：267 / 300
页数：34
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