Stannasiloxanes: from rings to polymers

被引：97
作者：
Beckmann, J [1 ]
Jurkschat, K [1 ]
机构：
[1] Univ Dortmund, Lehrstuhl Anorgan Chem 2, D-44221 Dortmund, Germany
来源：
COORDINATION CHEMISTRY REVIEWS | 2001年 / 215卷
关键词：
silicon; tin; siloxane; polymerization;
D O I：
10.1016/S0010-8545(01)00319-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A review is given with 140 references on the recent progress in the chemistry of cyclo-stannasiloxanes of different ring size, such as cyclo-R2Sn(OSiR2')(2)O, cyclo-R2Sn(OSiPh2O)(2)SnR2, cycle -R2Sn(OSiPh2O)(2)SiPh2, cycle -R2Sn(OSiPh2)(2)SiPh2 and cyclo-R2Sn(OSiPh2)(2) (R = alkyl, aryl, intramolecularly coordinating built-in ligand, transition metal fragment; R ' =Me, i-Pr, Ph); and their potential in ring-opening polymerization reactions is critically evaluated and compared with that of related cyclo-borasiloxanes, cyclo-germasiloxanes, and cyclo-siloxanes. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：267 / 300
页数：34
相关论文
共 139 条
  • [1] A 12-membered inorganic heterocycle: Synthesis and structural characterization of a bimetallic Chromium(VI) siloxane complex
    Abbenhuis, HCL
    Vorstenbosch, MLW
    van Santen, RA
    Smeets, WJJ
    Spek, AL
    [J]. INORGANIC CHEMISTRY, 1997, 36 (27) : 6431 - 6433
  • [2] SYNTHESIS AND CRYSTAL-STRUCTURES OF THE CYCLOSILOXYTIN(IV) COMPLEXES [CL2SN(O(SIPH(2)O)(2))(2)]-MU-(LI(THF)(2))(2)] AND [THF2SN((OSIPH(2))(3)O)(2)]CENTER-DOT-TOLUENE
    ABRAHAMS, I
    MOTEVALLI, M
    SHAH, SAA
    SULLIVAN, AC
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 492 (01) : 99 - 104
  • [3] STRUCTURE OF DIETHYLGERMANIUM DIPHENYLSILICON OXIDE AND CONFORMATION OF 8-MEMBERED RINGS WITH SILICON AND GERMANIUM
    AKKURT, M
    KOK, TR
    FALESCHINI, P
    RANDACCIO, L
    PUFF, H
    SCHUH, W
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 470 (1-2) : 59 - 66
  • [4] Allcock H. R., 1992, J INORG ORGANOMET P, V2, P197, DOI 10.1007/BF00696547
  • [5] Allcock H. R., 1993, RING OPENING POLYM, P217
  • [6] INORGANIC-ORGANIC POLYMERS
    ALLCOCK, HR
    [J]. ADVANCED MATERIALS, 1994, 6 (02) : 106 - 115
  • [7] ELECTRONEGATIVITIES OF CARBON, SILICON, GERMANIUM, TIN AND LEAD
    ALLRED, AL
    ROCHOW, EG
    [J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1958, 5 (04): : 269 - 288
  • [8] ANDRIANOV AA, 1965, ZH OBSHCH KHIM, V35, P330
  • [9] THERMALLY RESISTANT POLYMERS
    ATLAS, SM
    MARK, HF
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1960, 72 (7-8) : 249 - 255
  • [10] TIN SULFUR AND TIN SELENIUM PHENYLATED RING-SYSTEMS AS ORGANOMETALLIC PRECURSORS TO TIN SULFIDE AND TIN SELENIDE
    BAHR, SR
    BOUDJOUK, P
    MCCARTHY, GJ
    [J]. CHEMISTRY OF MATERIALS, 1992, 4 (02) : 383 - 388
12345678910